Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands

D  BARR; M J  DOYLE; Robert Mulvey; P R  RAITHBY; R  SNAITH; D S  WRIGHT

doi:10.1039/C39880000145

Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands

D BARR, M J DOYLE, Robert Mulvey, P R RAITHBY, R SNAITH, D S WRIGHT

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The anhydrous complex (LiSCN·TMEDA)n(1)[TMEDA = Me2N(CH2)2NMe2] has been synthesised by a novel in situ route from solid NH4SCN and BunLi in TMEDA/hexane, and shown to have a polymeric chain crystal structure with Li–N[graphic omitted]CS Li repeat units; in hydrocarbon solvents, however, (1) adopts a dimeric, purely N–Li bridged structure.

Original language	English
Pages (from-to)	145-147
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39880000145
Publication status	Published - 15 Jan 1988

Keywords

lithium thiocyanate
polymeric solid
solution structures
crystal structures

Access to Document

10.1039/C39880000145

Fingerprint

Dive into the research topics of 'Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands'. Together they form a unique fingerprint.

Cite this

BARR, D., DOYLE, M. J., Mulvey, R., RAITHBY, P. R., SNAITH, R., & WRIGHT, D. S. (1988). Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands. Journal of the Chemical Society, Chemical Communications, (2), 145-147. https://doi.org/10.1039/C39880000145

@article{f909723a461c48f6b070f61633135713,

title = "Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands",

abstract = "The anhydrous complex (LiSCN·TMEDA)n(1)[TMEDA = Me2N(CH2)2NMe2] has been synthesised by a novel in situ route from solid NH4SCN and BunLi in TMEDA/hexane, and shown to have a polymeric chain crystal structure with Li–N[graphic omitted]CS Li repeat units; in hydrocarbon solvents, however, (1) adopts a dimeric, purely N–Li bridged structure.",

keywords = "lithium thiocyanate , polymeric solid , solution structures, crystal structures",

author = "D BARR and DOYLE, {M J} and Robert Mulvey and RAITHBY, {P R} and R SNAITH and WRIGHT, {D S}",

year = "1988",

month = jan,

day = "15",

doi = "10.1039/C39880000145",

language = "English",

pages = "145--147",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "2",

}

BARR, D, DOYLE, MJ, Mulvey, R, RAITHBY, PR, SNAITH, R & WRIGHT, DS 1988, 'Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands', Journal of the Chemical Society, Chemical Communications, no. 2, pp. 145-147. https://doi.org/10.1039/C39880000145

Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands. / BARR, D ; DOYLE, M J ; Mulvey, Robert et al.
In: Journal of the Chemical Society, Chemical Communications, No. 2, 15.01.1988, p. 145-147.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands

AU - BARR, D

AU - DOYLE, M J

AU - Mulvey, Robert

AU - RAITHBY, P R

AU - SNAITH, R

AU - WRIGHT, D S

PY - 1988/1/15

Y1 - 1988/1/15

N2 - The anhydrous complex (LiSCN·TMEDA)n(1)[TMEDA = Me2N(CH2)2NMe2] has been synthesised by a novel in situ route from solid NH4SCN and BunLi in TMEDA/hexane, and shown to have a polymeric chain crystal structure with Li–N[graphic omitted]CS Li repeat units; in hydrocarbon solvents, however, (1) adopts a dimeric, purely N–Li bridged structure.

AB - The anhydrous complex (LiSCN·TMEDA)n(1)[TMEDA = Me2N(CH2)2NMe2] has been synthesised by a novel in situ route from solid NH4SCN and BunLi in TMEDA/hexane, and shown to have a polymeric chain crystal structure with Li–N[graphic omitted]CS Li repeat units; in hydrocarbon solvents, however, (1) adopts a dimeric, purely N–Li bridged structure.

KW - lithium thiocyanate

KW - polymeric solid

KW - solution structures

KW - crystal structures

U2 - 10.1039/C39880000145

DO - 10.1039/C39880000145

M3 - Article

SN - 0022-4936

SP - 145

EP - 147

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 2

ER -

BARR D, DOYLE MJ, Mulvey R, RAITHBY PR, SNAITH R, WRIGHT DS. Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands. Journal of the Chemical Society, Chemical Communications. 1988 Jan 15;(2):145-147. doi: 10.1039/C39880000145