Synthesis and characterization of isomerically pure anti- and syn-anthradiindole derivatives

Jean-Yves Balandier; Nicolas Henry; Jean-Baptiste Arlin; Lionel Sanguinet; Vincent Lemaur; Claude Niebel; Basab Chattopadhyay; Alan Robert Kennedy; Philippe Leriche; Philippe Blanchard; Jerome Cornill; Yves Henri Geerts

doi:10.1021/ol303214j

Synthesis and characterization of isomerically pure anti- and syn-anthradiindole derivatives

Jean-Yves Balandier
, Nicolas Henry
, Jean-Baptiste Arlin
, Lionel Sanguinet
, Vincent Lemaur
, Claude Niebel
, Basab Chattopadhyay
, Alan Robert Kennedy
, Philippe Leriche
, Philippe Blanchard
, Jerome Cornill
, Yves Henri Geerts

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Synthesis, isolation, and characterization of isomerically pure syn- and anti-anthradiindole (ADI) derivatives are described. The anti- and syn-ADI structures are demonstrated by C-13 NMR spectroscopy and by single-crystal X-ray diffraction. The spectroscopic and electrochemical properties as well as the stability of these newly synthesized pi-conjugated systems are evaluated and supported by quantum-chemical calculations.

Original language	English
Pages (from-to)	302-305
Number of pages	4
Journal	Organic Letters
Volume	15
Issue number	2
Early online date	9 Jan 2013
DOIs	https://doi.org/10.1021/ol303214j
Publication status	Published - 18 Jan 2013

Keywords

synthesis
characterization
isomerically pure
anti- and syn-anthradiindole derivatives

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10.1021/ol303214j

Cite this

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title = "Synthesis and characterization of isomerically pure anti- and syn-anthradiindole derivatives",

abstract = "Synthesis, isolation, and characterization of isomerically pure syn- and anti-anthradiindole (ADI) derivatives are described. The anti- and syn-ADI structures are demonstrated by C-13 NMR spectroscopy and by single-crystal X-ray diffraction. The spectroscopic and electrochemical properties as well as the stability of these newly synthesized pi-conjugated systems are evaluated and supported by quantum-chemical calculations.",

keywords = "synthesis, characterization, isomerically pure, anti- and syn-anthradiindole derivatives",

author = "Jean-Yves Balandier and Nicolas Henry and Jean-Baptiste Arlin and Lionel Sanguinet and Vincent Lemaur and Claude Niebel and Basab Chattopadhyay and Kennedy, \{Alan Robert\} and Philippe Leriche and Philippe Blanchard and Jerome Cornill and Geerts, \{Yves Henri\}",

year = "2013",

month = jan,

day = "18",

doi = "10.1021/ol303214j",

language = "English",

volume = "15",

pages = "302--305",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "2",

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TY - JOUR

T1 - Synthesis and characterization of isomerically pure anti- and syn-anthradiindole derivatives

AU - Balandier, Jean-Yves

AU - Henry, Nicolas

AU - Arlin, Jean-Baptiste

AU - Sanguinet, Lionel

AU - Lemaur, Vincent

AU - Niebel, Claude

AU - Chattopadhyay, Basab

AU - Kennedy, Alan Robert

AU - Leriche, Philippe

AU - Blanchard, Philippe

AU - Cornill, Jerome

AU - Geerts, Yves Henri

PY - 2013/1/18

Y1 - 2013/1/18

N2 - Synthesis, isolation, and characterization of isomerically pure syn- and anti-anthradiindole (ADI) derivatives are described. The anti- and syn-ADI structures are demonstrated by C-13 NMR spectroscopy and by single-crystal X-ray diffraction. The spectroscopic and electrochemical properties as well as the stability of these newly synthesized pi-conjugated systems are evaluated and supported by quantum-chemical calculations.

AB - Synthesis, isolation, and characterization of isomerically pure syn- and anti-anthradiindole (ADI) derivatives are described. The anti- and syn-ADI structures are demonstrated by C-13 NMR spectroscopy and by single-crystal X-ray diffraction. The spectroscopic and electrochemical properties as well as the stability of these newly synthesized pi-conjugated systems are evaluated and supported by quantum-chemical calculations.

KW - synthesis

KW - characterization

KW - isomerically pure

KW - anti- and syn-anthradiindole derivatives

UR - https://www.scopus.com/pages/publications/84872581093

U2 - 10.1021/ol303214j

DO - 10.1021/ol303214j

M3 - Article

SN - 1523-7060

VL - 15

SP - 302

EP - 305

JO - Organic Letters

JF - Organic Letters

IS - 2

ER -

Synthesis and characterization of isomerically pure anti- and syn-anthradiindole derivatives

Abstract

Keywords

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Synthesis and characterization of isomerically pure anti- and syn-anthradiindole derivatives

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Keywords

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