Synthesis and characterization of isomerically pure anti- and syn-anthradiindole derivatives

Jean-Yves Balandier, Nicolas Henry, Jean-Baptiste Arlin, Lionel Sanguinet, Vincent Lemaur, Claude Niebel, Basab Chattopadhyay, Alan Robert Kennedy, Philippe Leriche, Philippe Blanchard, Jerome Cornill, Yves Henri Geerts

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

Synthesis, isolation, and characterization of isomerically pure syn- and anti-anthradiindole (ADI) derivatives are described. The anti- and syn-ADI structures are demonstrated by C-13 NMR spectroscopy and by single-crystal X-ray diffraction. The spectroscopic and electrochemical properties as well as the stability of these newly synthesized pi-conjugated systems are evaluated and supported by quantum-chemical calculations.

Original languageEnglish
Pages (from-to)302-305
Number of pages4
JournalOrganic Letters
Volume15
Issue number2
Early online date9 Jan 2013
DOIs
Publication statusPublished - 18 Jan 2013

Keywords

  • synthesis
  • characterization
  • isomerically pure
  • anti- and syn-anthradiindole derivatives

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