Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

Sharon E. Baillie; William Clegg; Pablo Garcia-Alvarez; Eva Hevia; Alan R. Kennedy; Jan Klett; Luca Russo

doi:10.1039/c0cc02164d

Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

Sharon E. Baillie, William Clegg, Pablo Garcia-Alvarez, Eva Hevia, Alan R. Kennedy, Jan Klett, Luca Russo

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).

Original language	English
Pages (from-to)	388-390
Number of pages	3
Journal	Chemical Communications (London)
Volume	47
Issue number	1
DOIs	https://doi.org/10.1039/c0cc02164d
Publication status	Published - 2011

Keywords

trisalkylmagnesiate
metal-alkyl bonds
alkali-metal trisalkylmagnesiate

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10.1039/c0cc02164d

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title = "Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate",

abstract = "The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [\{NaMg(CH2SiMe3)(3)\}(infinity)] (1) as well as the related solvent-free sodium alkyl [\{(NaCH2SiMe3)(4)\}(infinity)] (3).",

keywords = "trisalkylmagnesiate, metal-alkyl bonds , alkali-metal trisalkylmagnesiate",

author = "Baillie, \{Sharon E.\} and William Clegg and Pablo Garcia-Alvarez and Eva Hevia and Kennedy, \{Alan R.\} and Jan Klett and Luca Russo",

year = "2011",

doi = "10.1039/c0cc02164d",

language = "English",

volume = "47",

pages = "388--390",

journal = "Chemical Communications (London)",

issn = "0009-241X",

publisher = "Chemical Society",

number = "1",

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TY - JOUR

T1 - Synthesis and characterization of an infinite sheet of metal-alkyl bonds

T2 - unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

AU - Baillie, Sharon E.

AU - Clegg, William

AU - Garcia-Alvarez, Pablo

AU - Hevia, Eva

AU - Kennedy, Alan R.

AU - Klett, Jan

AU - Russo, Luca

PY - 2011

Y1 - 2011

N2 - The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).

AB - The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).

KW - trisalkylmagnesiate

KW - metal-alkyl bonds

KW - alkali-metal trisalkylmagnesiate

UR - https://www.scopus.com/pages/publications/78649845932

U2 - 10.1039/c0cc02164d

DO - 10.1039/c0cc02164d

M3 - Article

SN - 0009-241X

VL - 47

SP - 388

EP - 390

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 1

ER -

Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

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Keywords

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Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate

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Keywords

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