Abstract
The study of co-complexation reactions between NaCH2SiMe3 and Mg(CH2SiMe3)(2) has allowed the isolation and structural elucidation of the first solvent-free alkali-metal alkylmagnesiate [{NaMg(CH2SiMe3)(3)}(infinity)] (1) as well as the related solvent-free sodium alkyl [{(NaCH2SiMe3)(4)}(infinity)] (3).
Original language | English |
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Pages (from-to) | 388-390 |
Number of pages | 3 |
Journal | Chemical Communications (London) |
Volume | 47 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2011 |
Keywords
- trisalkylmagnesiate
- metal-alkyl bonds
- alkali-metal trisalkylmagnesiate