Abstract
| Language | English |
|---|---|
| Title of host publication | Organometallic Chemistry |
| Editors | Ian J S Fairlamb, Jason M Lynam |
| Pages | 1-26 |
| Number of pages | 26 |
| Volume | 37 |
| DOIs | |
| Publication status | Published - 2011 |
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Keywords
- synergistic effects
- activation
- small molecules
- s-block element
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Synergistic effects in the activation of small molecules by s-block elements. / O'Hara, Charles.
Organometallic Chemistry. ed. / Ian J S Fairlamb; Jason M Lynam. Vol. 37 2011. p. 1-26.Research output: Chapter in Book/Report/Conference proceeding › Chapter
TY - CHAP
T1 - Synergistic effects in the activation of small molecules by s-block elements
AU - O'Hara, Charles
PY - 2011
Y1 - 2011
N2 - This critical review covers recent developments in the special chemistry which can take place when two different s-block metals are combined within the same organometallic mixture or reagent. It will cover a selection of the most widely researched mixed-metal ‘synergic’ systems, and will be confined to mixed alkali metal/magnesium reagents. An overview of the known structural chemistry of these fascinating systems will be presented along with some of their pertinent, recent uses in synthesis, including, in the activation/cleavage of C-H bonds (i.e., a metallation reaction) or induction of metal-halogen exchange in organic molecules. The chapter begins by providing a brief historical overview of mixed s-block metal chemistry.
AB - This critical review covers recent developments in the special chemistry which can take place when two different s-block metals are combined within the same organometallic mixture or reagent. It will cover a selection of the most widely researched mixed-metal ‘synergic’ systems, and will be confined to mixed alkali metal/magnesium reagents. An overview of the known structural chemistry of these fascinating systems will be presented along with some of their pertinent, recent uses in synthesis, including, in the activation/cleavage of C-H bonds (i.e., a metallation reaction) or induction of metal-halogen exchange in organic molecules. The chapter begins by providing a brief historical overview of mixed s-block metal chemistry.
KW - synergistic effects
KW - activation
KW - small molecules
KW - s-block element
U2 - 10.1039/9781849732802-00001
DO - 10.1039/9781849732802-00001
M3 - Chapter
SN - 9781849732802
VL - 37
SP - 1
EP - 26
BT - Organometallic Chemistry
A2 - Fairlamb, Ian J S
A2 - Lynam, Jason M
ER -