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Abstract
Four bonds in total, two NH and two CH bonds, have been cleaved from a neutral secondary diamine through the cooperative effects of a lithium alkyl–zinc bisalkyl coalition aided by N,N,N′,N′-tetramethylethylenediamine (TMEDA) to generate a dianionic diazaethene.
| Original language | English |
|---|---|
| Pages (from-to) | 9964-9968 |
| Number of pages | 5 |
| Journal | Chemistry - A European Journal |
| Volume | 16 |
| Issue number | 33 |
| DOIs | |
| Publication status | Published - 3 Sep 2010 |
Keywords
- amines
- hydrides
- lithium
- metallacycles
- zinc
- directed ortho-metalation
- mediated zincation
- deprotonative matalation
- functionalized aromatics
- complexes
- magnesium
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Projects
- 1 Finished