Projects per year
Abstract
Four bonds in total, two NH and two CH bonds, have been cleaved from a neutral secondary diamine through the cooperative effects of a lithium alkyl–zinc bisalkyl coalition aided by N,N,N′,N′-tetramethylethylenediamine (TMEDA) to generate a dianionic diazaethene.
Original language | English |
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Pages (from-to) | 9964-9968 |
Number of pages | 5 |
Journal | Chemistry - A European Journal |
Volume | 16 |
Issue number | 33 |
DOIs | |
Publication status | Published - 3 Sept 2010 |
Keywords
- amines
- hydrides
- lithium
- metallacycles
- zinc
- directed ortho-metalation
- mediated zincation
- deprotonative matalation
- functionalized aromatics
- complexes
- magnesium
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Dive into the research topics of 'Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture'. Together they form a unique fingerprint.Projects
- 1 Finished
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EXPLOITING SYNTHETIC AND STRUCTURAL SYNERGISM IN ALKALI-METAL-MEDIATED ORGANOTRANSITIONMETALLATION (AMMO)
Mulvey, R. (Principal Investigator) & Kennedy, A. (Co-investigator)
EPSRC (Engineering and Physical Sciences Research Council)
1/10/08 → 31/03/12
Project: Research