Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation

E. Hevia; David R. Armstrong; A. Kennedy; R.E. Mulvey

doi:10.1021/om060216v

Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation

E. Hevia, David R. Armstrong, A. Kennedy, R.E. Mulvey

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Bis(toluene)chromium is regioselectiVely deprotonated at the para position on one ring only by a mixed sodiummagnesium alkyl bis(amide) TMEDA actiVated synergic base in a reaction influenced by the Na···π-arene contacts present
in the crystalline trimetallic product.

Original language	English
Pages (from-to)	2415-2418
Number of pages	4
Journal	Organometallics
Volume	25
DOIs	https://doi.org/10.1021/om060216v
Publication status	Published - 2006

Keywords

metalation
organometalloidal compounds

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10.1021/om060216v

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@article{eb3decb68cf845408ab0daba12680db8,

title = "Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation",

abstract = "Bis(toluene)chromium is regioselectiVely deprotonated at the para position on one ring only by a mixed sodiummagnesium alkyl bis(amide) TMEDA actiVated synergic base in a reaction influenced by the Na···π-arene contacts presentin the crystalline trimetallic product.",

keywords = "metalation, organometalloidal compounds",

author = "E. Hevia and Armstrong, {David R.} and A. Kennedy and R.E. Mulvey",

year = "2006",

doi = "10.1021/om060216v",

language = "English",

volume = "25",

pages = "2415--2418",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

}

TY - JOUR

T1 - Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation

AU - Hevia, E.

AU - Armstrong, David R.

AU - Kennedy, A.

AU - Mulvey, R.E.

PY - 2006

Y1 - 2006

N2 - Bis(toluene)chromium is regioselectiVely deprotonated at the para position on one ring only by a mixed sodiummagnesium alkyl bis(amide) TMEDA actiVated synergic base in a reaction influenced by the Na···π-arene contacts presentin the crystalline trimetallic product.

AB - Bis(toluene)chromium is regioselectiVely deprotonated at the para position on one ring only by a mixed sodiummagnesium alkyl bis(amide) TMEDA actiVated synergic base in a reaction influenced by the Na···π-arene contacts presentin the crystalline trimetallic product.

KW - metalation

KW - organometalloidal compounds

UR - http://dx.doi.org/10.1021/om060216v

U2 - 10.1021/om060216v

DO - 10.1021/om060216v

M3 - Article

VL - 25

SP - 2415

EP - 2418

JO - Organometallics

JF - Organometallics

SN - 0276-7333

ER -

Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation

Abstract

Keywords

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