Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation

E. Hevia, David R. Armstrong, A. Kennedy, R.E. Mulvey

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Bis(toluene)chromium is regioselectiVely deprotonated at the para position on one ring only by a mixed sodiummagnesium alkyl bis(amide) TMEDA actiVated synergic base in a reaction influenced by the Na···π-arene contacts present
in the crystalline trimetallic product.
LanguageEnglish
Pages2415-2418
Number of pages4
JournalOrganometallics
Volume25
DOIs
Publication statusPublished - 2006

Fingerprint

Alkali Metals
Toluene
Chromium
Amides
alkali metals
amides
toluene
chromium
Crystalline materials
rings
products
phenyllithium

Keywords

  • metalation
  • organometalloidal compounds

Cite this

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abstract = "Bis(toluene)chromium is regioselectiVely deprotonated at the para position on one ring only by a mixed sodiummagnesium alkyl bis(amide) TMEDA actiVated synergic base in a reaction influenced by the Na···π-arene contacts presentin the crystalline trimetallic product.",
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Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation. / Hevia, E.; Armstrong, David R.; Kennedy, A.; Mulvey, R.E.

In: Organometallics, Vol. 25, 2006, p. 2415-2418.

Research output: Contribution to journalArticle

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T1 - Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation

AU - Hevia, E.

AU - Armstrong, David R.

AU - Kennedy, A.

AU - Mulvey, R.E.

PY - 2006

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AB - Bis(toluene)chromium is regioselectiVely deprotonated at the para position on one ring only by a mixed sodiummagnesium alkyl bis(amide) TMEDA actiVated synergic base in a reaction influenced by the Na···π-arene contacts presentin the crystalline trimetallic product.

KW - metalation

KW - organometalloidal compounds

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