Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation

E. Hevia, David R. Armstrong, A. Kennedy, R.E. Mulvey

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Bis(toluene)chromium is regioselectiVely deprotonated at the para position on one ring only by a mixed sodiummagnesium alkyl bis(amide) TMEDA actiVated synergic base in a reaction influenced by the Na···π-arene contacts present
in the crystalline trimetallic product.
Original languageEnglish
Pages (from-to)2415-2418
Number of pages4
JournalOrganometallics
Volume25
DOIs
Publication statusPublished - 2006

Keywords

  • metalation
  • organometalloidal compounds

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