Supramolecular study, Hirshfeld analysis and theoretical study of 6-methoxyquinoline N-oxide dihydrate

Rodolfo Moreno-Fuquen, Geraldine Hernandez, Alan Kennedy, Catriona A. Morrison

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Abstract

In the crystal structure of 6-methoxyquinoline N-oxide dihydrate, C10H9NO2 center dot 2H(2)O, (I), the presence of two-dimensional water networks is analysed. The water molecules form unusual water channels, as well as two intersecting mutually perpendicular columns. In one of these channels, the O atom of the N-oxide group acts as a bridge between the water molecules. The other channel is formed exclusively by water molecules. Confirmation of the molecular packing was performed through the analysis of Hirshfeld surfaces, and (I) is compared with other similar isoquinoline systems. Calculations of bond lengths and angles by the Hartree-Fock method or by density functional theory B3LYP, both with 6-311++G(d,p) basis sets, are reported, together with the results of additional IR, UV-Vis and theoretical studies.

Original languageEnglish
Pages (from-to)665-670
Number of pages6
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume69
Issue number6
DOIs
Publication statusPublished - Jun 2013

Keywords

  • acid
  • crystal structures
  • intermolecular interactions
  • quinoline

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