Super-selective polysulfone hollow fibre membranes for gas separation: assessment of molecular orientation by Raman spectroscopy

Sergey Gordeyev; G.Y. Nikolaeva; K.A. Prokhorov; Rob Withnall; Ian Dunkin; Simon Shilton

Super-selective polysulfone hollow fibre membranes for gas separation: assessment of molecular orientation by Raman spectroscopy

Sergey Gordeyev, G.Y. Nikolaeva, K.A. Prokhorov, Rob Withnall, Ian Dunkin, Simon Shilton

Research output: Contribution to journal › Article › peer-review

Abstract

It has been shown that the polarized Raman scattering method previously developed for quantitative analysis of molecular orientation in polyethylene can be applied to polysulfone hollow ﬁbre membranes. The orientation parameters for the in-plane vibration of the benzene ring in the active layers of the membranes were
determined for different processing conditions of the ﬁbres. The results reported here conﬁrm the fact, revealed previously by IR spectroscopy, that the spinning of membrane ﬁbres at high shear rates may induce anisotropy at the molecular level in the active layer.

Original language	English
Pages (from-to)	82-85
Number of pages	4
Journal	Laser Physics
Volume	11
Issue number	1
Publication status	Published - 2001

Keywords

fibre membranes
gas separation
Raman scattering
spectroscopy

Cite this

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title = "Super-selective polysulfone hollow fibre membranes for gas separation: assessment of molecular orientation by Raman spectroscopy",

abstract = "It has been shown that the polarized Raman scattering method previously developed for quantitative analysis of molecular orientation in polyethylene can be applied to polysulfone hollow ﬁbre membranes. The orientation parameters for the in-plane vibration of the benzene ring in the active layers of the membranes weredetermined for different processing conditions of the ﬁbres. The results reported here conﬁrm the fact, revealed previously by IR spectroscopy, that the spinning of membrane ﬁbres at high shear rates may induce anisotropy at the molecular level in the active layer.",

keywords = "fibre membranes , gas separation, Raman scattering , spectroscopy",

author = "Sergey Gordeyev and G.Y. Nikolaeva and K.A. Prokhorov and Rob Withnall and Ian Dunkin and Simon Shilton",

year = "2001",

language = "English",

volume = "11",

pages = "82--85",

journal = "Laser Physics",

issn = "1054-660X",

number = "1",

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TY - JOUR

T1 - Super-selective polysulfone hollow fibre membranes for gas separation: assessment of molecular orientation by Raman spectroscopy

AU - Gordeyev, Sergey

AU - Nikolaeva, G.Y.

AU - Prokhorov, K.A.

AU - Withnall, Rob

AU - Dunkin, Ian

AU - Shilton, Simon

PY - 2001

Y1 - 2001

N2 - It has been shown that the polarized Raman scattering method previously developed for quantitative analysis of molecular orientation in polyethylene can be applied to polysulfone hollow ﬁbre membranes. The orientation parameters for the in-plane vibration of the benzene ring in the active layers of the membranes weredetermined for different processing conditions of the ﬁbres. The results reported here conﬁrm the fact, revealed previously by IR spectroscopy, that the spinning of membrane ﬁbres at high shear rates may induce anisotropy at the molecular level in the active layer.

AB - It has been shown that the polarized Raman scattering method previously developed for quantitative analysis of molecular orientation in polyethylene can be applied to polysulfone hollow ﬁbre membranes. The orientation parameters for the in-plane vibration of the benzene ring in the active layers of the membranes weredetermined for different processing conditions of the ﬁbres. The results reported here conﬁrm the fact, revealed previously by IR spectroscopy, that the spinning of membrane ﬁbres at high shear rates may induce anisotropy at the molecular level in the active layer.

KW - fibre membranes

KW - gas separation

KW - Raman scattering

KW - spectroscopy

UR - http://www.maik.ru/full/lasphys/01/1/lasphys1_01p82full.pdf

M3 - Article

SN - 1054-660X

VL - 11

SP - 82

EP - 85

JO - Laser Physics

JF - Laser Physics

IS - 1

ER -

Super-selective polysulfone hollow fibre membranes for gas separation: assessment of molecular orientation by Raman spectroscopy

Abstract

Keywords

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