Structures of the potassium aluminates [{K-2(Me(3)AlOBu(t))(2)center dot pmdeta}(infinity)] and [{K(pmdeta)(2)}(+)(AlMe(4))(-)]: how the nature of the alane reagent determines which of these products form from alkoxide-containing reaction mixtures

F J Craig, A R Kennedy, R E Mulvey, M D Spicer

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Equimolar mixtures of AlMe(3), Bu(t)OK, and pmdeta produce either title compound depending on whether solvent-free, dimeric [(AlMe(3))(2)] or the amine-solvated monomer [Me(3)Al .(H)N(CH(2)Ph)(2)] is used as the source of the alane.

Original languageEnglish
Pages (from-to)1951-1952
Number of pages2
JournalChemical Communications (London)
Issue number16
DOIs
Publication statusPublished - 21 Aug 1996

Keywords

  • alane reagent
  • alkoxide

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