Structures of the potassium aluminates [{K-2(Me(3)AlOBu(t))(2)center dot pmdeta}(infinity)] and [{K(pmdeta)(2)}(+)(AlMe(4))(-)]: how the nature of the alane reagent determines which of these products form from alkoxide-containing reaction mixtures

F J Craig, A R Kennedy, R E Mulvey, M D Spicer

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12 Citations (Scopus)

Abstract

Equimolar mixtures of AlMe(3), Bu(t)OK, and pmdeta produce either title compound depending on whether solvent-free, dimeric [(AlMe(3))(2)] or the amine-solvated monomer [Me(3)Al .(H)N(CH(2)Ph)(2)] is used as the source of the alane.

LanguageEnglish
Pages1951-1952
Number of pages2
JournalChemical Communications (London)
Issue number16
DOIs
Publication statusPublished - 21 Aug 1996

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Amines
Potassium
Monomers

Keywords

  • alane reagent
  • alkoxide

Cite this

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title = "Structures of the potassium aluminates [{K-2(Me(3)AlOBu(t))(2)center dot pmdeta}(infinity)] and [{K(pmdeta)(2)}(+)(AlMe(4))(-)]: how the nature of the alane reagent determines which of these products form from alkoxide-containing reaction mixtures",
abstract = "Equimolar mixtures of AlMe(3), Bu(t)OK, and pmdeta produce either title compound depending on whether solvent-free, dimeric [(AlMe(3))(2)] or the amine-solvated monomer [Me(3)Al .(H)N(CH(2)Ph)(2)] is used as the source of the alane.",
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AU - Craig, F J

AU - Kennedy, A R

AU - Mulvey, R E

AU - Spicer, M D

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AB - Equimolar mixtures of AlMe(3), Bu(t)OK, and pmdeta produce either title compound depending on whether solvent-free, dimeric [(AlMe(3))(2)] or the amine-solvated monomer [Me(3)Al .(H)N(CH(2)Ph)(2)] is used as the source of the alane.

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KW - alkoxide

U2 - 10.1039/CC9960001951

DO - 10.1039/CC9960001951

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T2 - Chemical Communications (London)

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