Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2

R.J. Cross; A.R. Kennedy; L.J. Manojlovic-Muir

doi:10.1107/S0108270192012666

Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2

R.J. Cross
, A.R. Kennedy
, L.J. Manojlovic-Muir

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In crystals of trans-aquacarbonylbis(triphenylphosphine) rhodium(I) perchlorate dichloromethane solvate, the cations and anions are linked through O---H..-O hydrogen bonds to form dimeric [Rh(PPha)2(CO)(OH2)]2[C104]2 units characterized by crystallographically imposed 6',. symmetry. The cationic complex displays a slightly distorted squareplanar geometry around the Rh atom. The water molecule coordinates: the Rh I centre at an Rh--O distance of 2.127 (4) A,.

Original language	English
Pages (from-to)	1146-1148
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	49
Issue number	6
DOIs	https://doi.org/10.1107/S0108270192012666
Publication status	Published - Jun 1993

Keywords

crystals
dichloromethane solvate
crystallographically
geometry
cationic

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10.1107/S0108270192012666

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title = "Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2",

abstract = "In crystals of trans-aquacarbonylbis(triphenylphosphine) rhodium(I) perchlorate dichloromethane solvate, the cations and anions are linked through O---H..-O hydrogen bonds to form dimeric [Rh(PPha)2(CO)(OH2)]2[C104]2 units characterized by crystallographically imposed 6',. symmetry. The cationic complex displays a slightly distorted squareplanar geometry around the Rh atom. The water molecule coordinates: the Rh I centre at an Rh--O distance of 2.127 (4) A,.",

keywords = "crystals, dichloromethane solvate, crystallographically, geometry, cationic",

author = "R.J. Cross and A.R. Kennedy and L.J. Manojlovic-Muir",

year = "1993",

month = jun,

doi = "10.1107/S0108270192012666",

language = "English",

volume = "49",

pages = "1146--1148",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

number = "6",

}

TY - JOUR

T1 - Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2

AU - Cross, R.J.

AU - Kennedy, A.R.

AU - Manojlovic-Muir, L.J.

PY - 1993/6

Y1 - 1993/6

N2 - In crystals of trans-aquacarbonylbis(triphenylphosphine) rhodium(I) perchlorate dichloromethane solvate, the cations and anions are linked through O---H..-O hydrogen bonds to form dimeric [Rh(PPha)2(CO)(OH2)]2[C104]2 units characterized by crystallographically imposed 6',. symmetry. The cationic complex displays a slightly distorted squareplanar geometry around the Rh atom. The water molecule coordinates: the Rh I centre at an Rh--O distance of 2.127 (4) A,.

AB - In crystals of trans-aquacarbonylbis(triphenylphosphine) rhodium(I) perchlorate dichloromethane solvate, the cations and anions are linked through O---H..-O hydrogen bonds to form dimeric [Rh(PPha)2(CO)(OH2)]2[C104]2 units characterized by crystallographically imposed 6',. symmetry. The cationic complex displays a slightly distorted squareplanar geometry around the Rh atom. The water molecule coordinates: the Rh I centre at an Rh--O distance of 2.127 (4) A,.

KW - crystals

KW - dichloromethane solvate

KW - crystallographically

KW - geometry

KW - cationic

UR - http://dx.doi.org/10.1107/S0108270192012666

U2 - 10.1107/S0108270192012666

DO - 10.1107/S0108270192012666

M3 - Article

SN - 0108-2701

VL - 49

SP - 1146

EP - 1148

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 6

ER -

Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2

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Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2

Abstract

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