Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2

R.J. Cross, A.R. Kennedy, L.J. Manojlovic-Muir

Research output: Contribution to journalArticle

Abstract

In crystals of trans-aquacarbonylbis(triphenylphosphine) rhodium(I) perchlorate dichloromethane solvate, the cations and anions are linked through O---H..-O hydrogen bonds to form dimeric [Rh(PPha)2(CO)(OH2)]2[C104]2 units characterized by crystallographically imposed 6',. symmetry. The cationic complex displays a slightly distorted squareplanar geometry around the Rh atom. The water molecule coordinates: the Rh I centre at an Rh--O distance of 2.127 (4) A,.
Original languageEnglish
Pages (from-to)1146-1148
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume49
Issue number6
DOIs
Publication statusPublished - Jun 1993

Keywords

  • crystals
  • dichloromethane solvate
  • crystallographically
  • geometry
  • cationic

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