Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]

W. Clegg, P.A. O'Neil, K.W. Henderson, Robert Mulvey

Research output: Contribution to journalArticle


trans-Tetrachlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium, [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans position relative to one another. Both hmpa groups bind to the Ti via their O atoms.

Original languageEnglish
Pages (from-to)2108-2109
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Issue number12
Publication statusPublished - 15 Dec 1993


  • crystal structure
  • titanium

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