Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]

W. Clegg; P.A. O'Neil; K.W. Henderson; Robert Mulvey

doi:10.1107/S0108270193006973

Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]

W. Clegg, P.A. O'Neil, K.W. Henderson, Robert Mulvey

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

trans-Tetrachlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium, [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans position relative to one another. Both hmpa groups bind to the Ti via their O atoms.

Original language	English
Pages (from-to)	2108-2109
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	49
Issue number	12
DOIs	https://doi.org/10.1107/S0108270193006973
Publication status	Published - 15 Dec 1993

Keywords

crystal structure
titanium

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10.1107/S0108270193006973

Cite this

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title = "Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]",

abstract = "trans-Tetrachlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium, [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans position relative to one another. Both hmpa groups bind to the Ti via their O atoms.",

keywords = "crystal structure, titanium",

author = "W. Clegg and P.A. O'Neil and K.W. Henderson and Robert Mulvey",

year = "1993",

month = dec,

day = "15",

doi = "10.1107/S0108270193006973",

language = "English",

volume = "49",

pages = "2108--2109",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

number = "12",

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TY - JOUR

T1 - Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]

AU - Clegg, W.

AU - O'Neil, P.A.

AU - Henderson, K.W.

AU - Mulvey, Robert

PY - 1993/12/15

Y1 - 1993/12/15

N2 - trans-Tetrachlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium, [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans position relative to one another. Both hmpa groups bind to the Ti via their O atoms.

AB - trans-Tetrachlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium, [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans position relative to one another. Both hmpa groups bind to the Ti via their O atoms.

KW - crystal structure

KW - titanium

U2 - 10.1107/S0108270193006973

DO - 10.1107/S0108270193006973

M3 - Article

SN - 0108-2701

VL - 49

SP - 2108

EP - 2109

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 12

ER -

Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]

Abstract

Keywords

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