Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]

W. Clegg, P.A. O'Neil, K.W. Henderson, Robert Mulvey

Research output: Contribution to journalArticle

Abstract

trans-Tetrachlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium, [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans position relative to one another. Both hmpa groups bind to the Ti via their O atoms.

LanguageEnglish
Pages2108-2109
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume49
Issue number12
DOIs
Publication statusPublished - 15 Dec 1993

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Hempa
Titanium
Metals
Ligands
Atoms
titanium tetrachloride

Keywords

  • crystal structure
  • titanium

Cite this

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title = "Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]",
abstract = "trans-Tetrachlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium, [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans position relative to one another. Both hmpa groups bind to the Ti via their O atoms.",
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author = "W. Clegg and P.A. O'Neil and K.W. Henderson and Robert Mulvey",
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journal = "Acta Crystallographica Section C: Crystal Structure Communications",
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Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]. / Clegg, W.; O'Neil, P.A.; Henderson, K.W.; Mulvey, Robert.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 49, No. 12, 15.12.1993, p. 2108-2109.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Structure of monomeric [TiCl4(hexamethylphosphoric triamide)2]

AU - Clegg, W.

AU - O'Neil, P.A.

AU - Henderson, K.W.

AU - Mulvey, Robert

PY - 1993/12/15

Y1 - 1993/12/15

N2 - trans-Tetrachlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium, [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans position relative to one another. Both hmpa groups bind to the Ti via their O atoms.

AB - trans-Tetrachlorobis(N,N,N',N',N'',N''-hexamethyl-phosphoric triamide-O)titanium, [TiCl4(hmpa)2], where hmpa is C6H18N3OP, is monomeric and octahedral about the metal centre with the hmpa ligands occupying a trans position relative to one another. Both hmpa groups bind to the Ti via their O atoms.

KW - crystal structure

KW - titanium

U2 - 10.1107/S0108270193006973

DO - 10.1107/S0108270193006973

M3 - Article

VL - 49

SP - 2108

EP - 2109

JO - Acta Crystallographica Section C: Crystal Structure Communications

T2 - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 12

ER -