Abstract
| Language | English |
|---|---|
| Pages | 3182-3184 |
| Number of pages | 3 |
| Journal | Angewandte Chemie |
| Volume | 49 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - 19 Apr 2010 |
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Keywords
- alkali metals
- aluminium
- amides
- metalation
- steric effects
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Structurally stimulated deprotonation/alumination of the TMP anion. / Conway, B.; Kennedy, A.R.; Mulvey, R.E.; Robertson, Stuart D.; Garcia Alvarez, Joaquin.
In: Angewandte Chemie, Vol. 49, No. 18, 19.04.2010, p. 3182-3184.Research output: Contribution to journal › Article
TY - JOUR
T1 - Structurally stimulated deprotonation/alumination of the TMP anion
AU - Conway, B.
AU - Kennedy, A.R.
AU - Mulvey, R.E.
AU - Robertson, Stuart D.
AU - Garcia Alvarez, Joaquin
PY - 2010/4/19
Y1 - 2010/4/19
N2 - Long utilized as a strong Brønsted base, the tetramethylpiperidine (TMP) anion is forced to convert to a Brønsted acid in the presence of a potassium–aluminate species. The new compound [(TMEDA)K(μ-TMP*)(μ-iBu)Al(iBu)] was obtained where TMP* represents a CH3- and NH-deprotonated dianionic variant of TMP.
AB - Long utilized as a strong Brønsted base, the tetramethylpiperidine (TMP) anion is forced to convert to a Brønsted acid in the presence of a potassium–aluminate species. The new compound [(TMEDA)K(μ-TMP*)(μ-iBu)Al(iBu)] was obtained where TMP* represents a CH3- and NH-deprotonated dianionic variant of TMP.
KW - alkali metals
KW - aluminium
KW - amides
KW - metalation
KW - steric effects
UR - http://www.scopus.com/inward/record.url?scp=77951614490&partnerID=8YFLogxK
U2 - 10.1002/anie.201000181
DO - 10.1002/anie.201000181
M3 - Article
VL - 49
SP - 3182
EP - 3184
JO - Angewandte Chemie International Edition
T2 - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 18
ER -