Structurally stimulated deprotonation/alumination of the TMP anion

B. Conway, A.R. Kennedy, R.E. Mulvey, Stuart D. Robertson, Joaquin Garcia Alvarez

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Long utilized as a strong Brønsted base, the tetramethylpiperidine (TMP) anion is forced to convert to a Brønsted acid in the presence of a potassium–aluminate species. The new compound [(TMEDA)K(μ-TMP*)(μ-iBu)Al(iBu)] was obtained where TMP* represents a CH3- and NH-deprotonated dianionic variant of TMP.
LanguageEnglish
Pages3182-3184
Number of pages3
JournalAngewandte Chemie
Volume49
Issue number18
DOIs
Publication statusPublished - 19 Apr 2010

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Anions
Potassium
Acids
phenyllithium

Keywords

  • alkali metals
  • aluminium
  • amides
  • metalation
  • steric effects

Cite this

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Structurally stimulated deprotonation/alumination of the TMP anion. / Conway, B.; Kennedy, A.R.; Mulvey, R.E.; Robertson, Stuart D.; Garcia Alvarez, Joaquin.

In: Angewandte Chemie, Vol. 49, No. 18, 19.04.2010, p. 3182-3184.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Structurally stimulated deprotonation/alumination of the TMP anion

AU - Conway, B.

AU - Kennedy, A.R.

AU - Mulvey, R.E.

AU - Robertson, Stuart D.

AU - Garcia Alvarez, Joaquin

PY - 2010/4/19

Y1 - 2010/4/19

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KW - alkali metals

KW - aluminium

KW - amides

KW - metalation

KW - steric effects

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U2 - 10.1002/anie.201000181

DO - 10.1002/anie.201000181

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VL - 49

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JF - Angewandte Chemie International Edition

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