Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products

W. Clegg, S.H. Dale, E. Hevia, L.M. Hogg, G.W. Honeyman, R.E. Mulvey, C.T. O'Hara, L. Russo

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

Zany zincation: Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X-ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes.
LanguageEnglish
Pages731-734
Number of pages3
JournalAngewandte Chemie
Volume47
Issue number4
DOIs
Publication statusPublished - 2008

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Nitriles
Anions
Salts
Sodium
Ions
Cations
X-Rays

Keywords

  • ion pairs
  • metalation
  • nitriles
  • sodium
  • zinc

Cite this

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abstract = "Zany zincation: Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X-ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes.",
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Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products. / Clegg, W.; Dale, S.H.; Hevia, E.; Hogg, L.M.; Honeyman, G.W.; Mulvey, R.E.; O'Hara, C.T.; Russo, L.

In: Angewandte Chemie, Vol. 47, No. 4, 2008, p. 731-734.

Research output: Contribution to journalArticle

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AU - Clegg, W.

AU - Dale, S.H.

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AU - Hogg, L.M.

AU - Honeyman, G.W.

AU - Mulvey, R.E.

AU - O'Hara, C.T.

AU - Russo, L.

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KW - metalation

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KW - zinc

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