Abstract
Zany zincation: Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X-ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes.
| Original language | English |
|---|---|
| Pages (from-to) | 731-734 |
| Number of pages | 3 |
| Journal | Angewandte Chemie |
| Volume | 47 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 2008 |
Keywords
- ion pairs
- metalation
- nitriles
- sodium
- zinc
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Clegg, W., Dale, S. H., Hevia, E., Hogg, L. M., Honeyman, G. W., Mulvey, R. E., O'Hara, C. T., & Russo, L. (2008). Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products. Angewandte Chemie, 47(4), 731-734. https://doi.org/10.1002/anie.200704341