Abstract
| Language | English |
|---|---|
| Pages | 731-734 |
| Number of pages | 3 |
| Journal | Angewandte Chemie |
| Volume | 47 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 2008 |
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Keywords
- ion pairs
- metalation
- nitriles
- sodium
- zinc
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Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products. / Clegg, W.; Dale, S.H.; Hevia, E.; Hogg, L.M.; Honeyman, G.W.; Mulvey, R.E.; O'Hara, C.T.; Russo, L.
In: Angewandte Chemie, Vol. 47, No. 4, 2008, p. 731-734.Research output: Contribution to journal › Article
TY - JOUR
T1 - Structurally defined reactions of sodium tmp-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products
AU - Clegg, W.
AU - Dale, S.H.
AU - Hevia, E.
AU - Hogg, L.M.
AU - Honeyman, G.W.
AU - Mulvey, R.E.
AU - O'Hara, C.T.
AU - Russo, L.
PY - 2008
Y1 - 2008
N2 - Zany zincation: Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X-ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes.
AB - Zany zincation: Seemingly simple zincation reactions of aromatic or aliphatic nitriles are in reality highly complicated affairs involving separated ion pairs (see X-ray structure; yellow Na, blue N, green Zn; left cation, right anion) or joined ion pairs. The results also show that the free zincate anions can engage in complicated dismutation processes.
KW - ion pairs
KW - metalation
KW - nitriles
KW - sodium
KW - zinc
UR - http://dx.doi.org/10.1002/anie.200704341
U2 - 10.1002/anie.200704341
DO - 10.1002/anie.200704341
M3 - Article
VL - 47
SP - 731
EP - 734
JO - Angewandte Chemie International Edition
T2 - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 4
ER -