Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines

B. Conway; D.V. Graham; E. Hevia; A.R. Kennedy; J. Klett; R.E. Mulvey

doi:10.1039/b805606d

Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines

B. Conway, D.V. Graham, E. Hevia, A.R. Kennedy, J. Klett, R.E. Mulvey

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

The new synergic base [PMDETA·K(TMP)(Et)Zn(Et)] selectively zincates 4-(dimethylamino)pyridine at the 2-position and 4-methoxypyridine at the 3-position, to afford bimetallic potassium pyridylzinc complexes each displaying a novel, but remarkably different, structure. (Abstract from: http://www.swetswise.com/eAccess/viewAbstract.do?articleID=37141954)

Original language	English
Pages (from-to)	2638-2640
Number of pages	2
Journal	Chemical Communications (London)
Issue number	23
DOIs	https://doi.org/10.1039/b805606d
Publication status	Published - 2008

Keywords

structurally-defined
potassium-mediated
regioselective
zincation
amino-and alkoxy-substituted pyridines

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10.1039/b805606d

Cite this

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title = "Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines",

abstract = "The new synergic base [PMDETA·K(TMP)(Et)Zn(Et)] selectively zincates 4-(dimethylamino)pyridine at the 2-position and 4-methoxypyridine at the 3-position, to afford bimetallic potassium pyridylzinc complexes each displaying a novel, but remarkably different, structure. (Abstract from: http://www.swetswise.com/eAccess/viewAbstract.do?articleID=37141954)",

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doi = "10.1039/b805606d",

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journal = "Chemical Communications (London)",

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TY - JOUR

T1 - Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines

AU - Conway, B.

AU - Graham, D.V.

AU - Hevia, E.

AU - Kennedy, A.R.

AU - Klett, J.

AU - Mulvey, R.E.

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N2 - The new synergic base [PMDETA·K(TMP)(Et)Zn(Et)] selectively zincates 4-(dimethylamino)pyridine at the 2-position and 4-methoxypyridine at the 3-position, to afford bimetallic potassium pyridylzinc complexes each displaying a novel, but remarkably different, structure. (Abstract from: http://www.swetswise.com/eAccess/viewAbstract.do?articleID=37141954)

AB - The new synergic base [PMDETA·K(TMP)(Et)Zn(Et)] selectively zincates 4-(dimethylamino)pyridine at the 2-position and 4-methoxypyridine at the 3-position, to afford bimetallic potassium pyridylzinc complexes each displaying a novel, but remarkably different, structure. (Abstract from: http://www.swetswise.com/eAccess/viewAbstract.do?articleID=37141954)

KW - structurally-defined

KW - potassium-mediated

KW - regioselective

KW - zincation

KW - amino-and alkoxy-substituted pyridines

UR - http://dx.doi.org/10.1039/b805606d

U2 - 10.1039/b805606d

DO - 10.1039/b805606d

M3 - Article

SN - 0009-241X

SP - 2638

EP - 2640

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 23

ER -

Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines

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Physical Organic Chemistry: Opportunities In Synthesis, Materials And Pharmaceuticals (Science And Innovation Award)

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Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines

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"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY

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x-ray diffractometer

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