Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines

B. Conway, D.V. Graham, E. Hevia, A.R. Kennedy, J. Klett, R.E. Mulvey

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

The new synergic base [PMDETA·K(TMP)(Et)Zn(Et)] selectively zincates 4-(dimethylamino)pyridine at the 2-position and 4-methoxypyridine at the 3-position, to afford bimetallic potassium pyridylzinc complexes each displaying a novel, but remarkably different, structure. (Abstract from: http://www.swetswise.com/eAccess/viewAbstract.do?articleID=37141954)
LanguageEnglish
Pages2638-2640
Number of pages2
JournalChemical Communications (London)
Issue number23
DOIs
Publication statusPublished - 2008

Fingerprint

Thymidine Monophosphate
Pyridines
Potassium
alkoxyl radical
pyridine
4-methoxypyridine

Keywords

  • structurally-defined
  • potassium-mediated
  • regioselective
  • zincation
  • amino-and alkoxy-substituted pyridines

Cite this

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abstract = "The new synergic base [PMDETA·K(TMP)(Et)Zn(Et)] selectively zincates 4-(dimethylamino)pyridine at the 2-position and 4-methoxypyridine at the 3-position, to afford bimetallic potassium pyridylzinc complexes each displaying a novel, but remarkably different, structure. (Abstract from: http://www.swetswise.com/eAccess/viewAbstract.do?articleID=37141954)",
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Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines. / Conway, B.; Graham, D.V.; Hevia, E.; Kennedy, A.R.; Klett, J.; Mulvey, R.E.

In: Chemical Communications (London), No. 23, 2008, p. 2638-2640.

Research output: Contribution to journalArticle

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T1 - Structurally-defined potassium-mediated regioselective zincation of amino-and alkoxy-substituted pyridines

AU - Conway, B.

AU - Graham, D.V.

AU - Hevia, E.

AU - Kennedy, A.R.

AU - Klett, J.

AU - Mulvey, R.E.

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KW - regioselective

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