Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts

W. Clegg, S.H. Dale, D.V. Graham, R.W. Harrington, E. Hevia, L.M. Hogg, A.R. Kennedy, R.E. Mulvey

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The first sodium-magnesium and sodium-zinc ketimido complexes display contrasting inverse crown ring and pseudo-cubane structures respectively, while a sodium-zinc heterotrianionic alkide-alkoxide-amide adopts a third type of structure with a stepped ladder motif.
LanguageEnglish
Pages1641-1643
Number of pages2
JournalChemical Communications (London)
Issue number16
DOIs
Publication statusPublished - 28 Apr 2007

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Amides
Magnesium
Zinc
Sodium
Ladders

Keywords

  • bimetallic sodium-magnesium
  • sodium-zinc ketimides
  • sodium-zinc alkide-alkoxide-amide
  • ring-stacking
  • ring-laddering
  • inverse crown

Cite this

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title = "Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts",
abstract = "The first sodium-magnesium and sodium-zinc ketimido complexes display contrasting inverse crown ring and pseudo-cubane structures respectively, while a sodium-zinc heterotrianionic alkide-alkoxide-amide adopts a third type of structure with a stepped ladder motif.",
keywords = "bimetallic sodium-magnesium, sodium-zinc ketimides, sodium-zinc alkide-alkoxide-amide, ring-stacking, ring-laddering, inverse crown",
author = "W. Clegg and S.H. Dale and D.V. Graham and R.W. Harrington and E. Hevia and L.M. Hogg and A.R. Kennedy and R.E. Mulvey",
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AU - Clegg, W.

AU - Dale, S.H.

AU - Graham, D.V.

AU - Harrington, R.W.

AU - Hevia, E.

AU - Hogg, L.M.

AU - Kennedy, A.R.

AU - Mulvey, R.E.

PY - 2007/4/28

Y1 - 2007/4/28

N2 - The first sodium-magnesium and sodium-zinc ketimido complexes display contrasting inverse crown ring and pseudo-cubane structures respectively, while a sodium-zinc heterotrianionic alkide-alkoxide-amide adopts a third type of structure with a stepped ladder motif.

AB - The first sodium-magnesium and sodium-zinc ketimido complexes display contrasting inverse crown ring and pseudo-cubane structures respectively, while a sodium-zinc heterotrianionic alkide-alkoxide-amide adopts a third type of structure with a stepped ladder motif.

KW - bimetallic sodium-magnesium

KW - sodium-zinc ketimides

KW - sodium-zinc alkide-alkoxide-amide

KW - ring-stacking

KW - ring-laddering

KW - inverse crown

UR - http://dx.doi.org/10.1039/b618609b

U2 - 10.1039/b618609b

DO - 10.1039/b618609b

M3 - Article

SP - 1641

EP - 1643

JO - Chemical Communications (London)

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