Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts

W. Clegg; S.H. Dale; D.V. Graham; R.W. Harrington; E. Hevia; L.M. Hogg; A.R. Kennedy; R.E. Mulvey

doi:10.1039/b618609b

Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts

W. Clegg, S.H. Dale, D.V. Graham, R.W. Harrington, E. Hevia, L.M. Hogg, A.R. Kennedy, R.E. Mulvey

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The first sodium-magnesium and sodium-zinc ketimido complexes display contrasting inverse crown ring and pseudo-cubane structures respectively, while a sodium-zinc heterotrianionic alkide-alkoxide-amide adopts a third type of structure with a stepped ladder motif.

Original language	English
Pages (from-to)	1641-1643
Number of pages	2
Journal	Chemical Communications (London)
Issue number	16
DOIs	https://doi.org/10.1039/b618609b
Publication status	Published - 28 Apr 2007

Keywords

bimetallic sodium-magnesium
sodium-zinc ketimides
sodium-zinc alkide-alkoxide-amide
ring-stacking
ring-laddering
inverse crown

Access to Document

10.1039/b618609b

http://dx.doi.org/10.1039/b618609b

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Clegg, W., Dale, S. H., Graham, D. V., Harrington, R. W., Hevia, E., Hogg, L. M., Kennedy, A. R., & Mulvey, R. E. (2007). Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts. Chemical Communications (London), (16), 1641-1643. https://doi.org/10.1039/b618609b

Clegg, W. ; Dale, S.H. ; Graham, D.V. ; Harrington, R.W. ; Hevia, E. ; Hogg, L.M. ; Kennedy, A.R. ; Mulvey, R.E. / Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts. In: Chemical Communications (London). 2007 ; No. 16. pp. 1641-1643.

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abstract = "The first sodium-magnesium and sodium-zinc ketimido complexes display contrasting inverse crown ring and pseudo-cubane structures respectively, while a sodium-zinc heterotrianionic alkide-alkoxide-amide adopts a third type of structure with a stepped ladder motif.",

keywords = "bimetallic sodium-magnesium, sodium-zinc ketimides, sodium-zinc alkide-alkoxide-amide, ring-stacking, ring-laddering, inverse crown",

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Clegg, W, Dale, SH, Graham, DV, Harrington, RW, Hevia, E, Hogg, LM, Kennedy, AR & Mulvey, RE 2007, 'Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts', Chemical Communications (London), no. 16, pp. 1641-1643. https://doi.org/10.1039/b618609b

Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, and inverse crown concepts. / Clegg, W.; Dale, S.H.; Graham, D.V.; Harrington, R.W.; Hevia, E.; Hogg, L.M.; Kennedy, A.R.; Mulvey, R.E.

In: Chemical Communications (London), No. 16, 28.04.2007, p. 1641-1643.

Research output: Contribution to journal › Article › peer-review

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KW - sodium-zinc alkide-alkoxide-amide

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KW - ring-laddering

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