Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 2317-2318 |
| Number of pages | 1 |
| Journal | Journal of the American Chemical Society |
| Volume | 121 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - 2 Mar 1999 |
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Keywords
- Tripodal ligands
- inorganic biochemistry
- ligand systems
- tridentate
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Structural consequences of the use of hard and soft tripodal ligands during metathesis reactions: Synthesis of the [bis(hydrotris(methimazolyl)borato]bismuth(III) [bis(hydrotris(pyrazolyl)borato]sodiate. / Reglinski, J.; Spicer, M.D.; Garner, M.; Kennedy, A.R.
In: Journal of the American Chemical Society, Vol. 121, No. 10, 02.03.1999, p. 2317-2318.Research output: Contribution to journal › Article
TY - JOUR
T1 - Structural consequences of the use of hard and soft tripodal ligands during metathesis reactions: Synthesis of the [bis(hydrotris(methimazolyl)borato]bismuth(III) [bis(hydrotris(pyrazolyl)borato]sodiate
AU - Reglinski, J.
AU - Spicer, M.D.
AU - Garner, M.
AU - Kennedy, A.R.
PY - 1999/3/2
Y1 - 1999/3/2
N2 - Tripodal ligands such as the hydrotris(pyrazolyl)borate anion (Tp) have found great favor in studies of structure and reactivity1 relevant to catalysis2 and inorganic biochemistry.3 Considering the accepted synthetic utility of Tp-based ligand systems, it is surprising that the range of analogous soft tripodal ligands is so limited.4 By replacing pyrazole with methimazole (2-mercapto-1-methylimidazole) in the synthetic method of Trofimenko5 (Scheme 1) we were recently successful6 in the direct synthesis of the simple tridentate, sulfur-based ligand, hydrotris(methimazolyl)borate (Tm).
AB - Tripodal ligands such as the hydrotris(pyrazolyl)borate anion (Tp) have found great favor in studies of structure and reactivity1 relevant to catalysis2 and inorganic biochemistry.3 Considering the accepted synthetic utility of Tp-based ligand systems, it is surprising that the range of analogous soft tripodal ligands is so limited.4 By replacing pyrazole with methimazole (2-mercapto-1-methylimidazole) in the synthetic method of Trofimenko5 (Scheme 1) we were recently successful6 in the direct synthesis of the simple tridentate, sulfur-based ligand, hydrotris(methimazolyl)borate (Tm).
KW - Tripodal ligands
KW - inorganic biochemistry
KW - ligand systems
KW - tridentate
UR - http://dx.doi.org/10.1021/ja983637f
U2 - 10.1021/ja983637f
DO - 10.1021/ja983637f
M3 - Article
VL - 121
SP - 2317
EP - 2318
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 10
ER -