Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure

V.L. Blair; A.R. Kennedy; J. Klett; R.E. Mulvey

doi:10.1039/b812147h

Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure

V.L. Blair, A.R. Kennedy, J. Klett, R.E. Mulvey

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)·Na(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium molecule [{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O)3(2-C4H3O)5}2], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands

Original language	English
Pages (from-to)	5426-5428
Number of pages	2
Journal	Chemical Communications (London)
Issue number	42
DOIs	https://doi.org/10.1039/b812147h
Publication status	Published - 2008

Keywords

magnesiation of furan

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10.1039/b812147h

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title = "Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure",

abstract = "Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)·Na(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium molecule [\{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O)3(2-C4H3O)5\}2], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands",

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author = "V.L. Blair and A.R. Kennedy and J. Klett and R.E. Mulvey",

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journal = "Chemical Communications (London)",

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T1 - Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure

AU - Blair, V.L.

AU - Kennedy, A.R.

AU - Klett, J.

AU - Mulvey, R.E.

PY - 2008

Y1 - 2008

N2 - Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)·Na(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium molecule [{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O)3(2-C4H3O)5}2], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands

AB - Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)·Na(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium molecule [{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O)3(2-C4H3O)5}2], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands

KW - magnesiation of furan

UR - http://dx.doi.org/10.1039/b812147h

U2 - 10.1039/b812147h

DO - 10.1039/b812147h

M3 - Article

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SP - 5426

EP - 5428

JO - Chemical Communications (London)

JF - Chemical Communications (London)

IS - 42

ER -

Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure

Abstract

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"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY

Mixed-Metal Molecular Synergy and its Application in Inverse Crown Chemistry

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Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure

Abstract

Keywords

Access to Document

Other files and links

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"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY

Mixed-Metal Molecular Synergy and its Application in Inverse Crown Chemistry

Cite this