Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure

V.L. Blair, A.R. Kennedy, J. Klett, R.E. Mulvey

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)·Na(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium molecule [{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O)3(2-C4H3O)5}2], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands
LanguageEnglish
Pages5426-5428
Number of pages2
JournalChemical Communications (London)
Issue number42
DOIs
Publication statusPublished - 2008

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Thymidine Monophosphate
Sodium
Ligands
Molecules
furan
phenyllithium

Keywords

  • magnesiation of furan

Cite this

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title = "Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure",
abstract = "Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)·Na(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium molecule [{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O)3(2-C4H3O)5}2], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands",
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author = "V.L. Blair and A.R. Kennedy and J. Klett and R.E. Mulvey",
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Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure. / Blair, V.L.; Kennedy, A.R.; Klett, J.; Mulvey, R.E.

In: Chemical Communications (London), No. 42, 2008, p. 5426-5428.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like mg-3(2,5-fur-di-yl)(3) substructure

AU - Blair, V.L.

AU - Kennedy, A.R.

AU - Klett, J.

AU - Mulvey, R.E.

PY - 2008

Y1 - 2008

N2 - Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)·Na(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium molecule [{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O)3(2-C4H3O)5}2], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands

AB - Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)·Na(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium molecule [{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O)3(2-C4H3O)5}2], built upon a bridge network of 10 monodeprotonated and 6 twofold-deprotonated furan ligands

KW - magnesiation of furan

UR - http://dx.doi.org/10.1039/b812147h

U2 - 10.1039/b812147h

DO - 10.1039/b812147h

M3 - Article

SP - 5426

EP - 5428

JO - Chemical Communications (London)

T2 - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

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ER -