Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex

D.W. Allen; R. Berridge; N. Bricklebank; S.D. Forder; F. Palacio; S.J. Coles; M.B. Hursthouse; P.J. Skabara

doi:10.1021/ic034092f

Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex

D.W. Allen
, R. Berridge
, N. Bricklebank
, S.D. Forder
, F. Palacio
, S.J. Coles
, M.B. Hursthouse
, P.J. Skabara

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented 'double' charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

Original language	English
Pages (from-to)	3975-3977
Number of pages	2
Journal	Inorganic Chemistry
Volume	42
Issue number	13
DOIs	https://doi.org/10.1021/ic034092f
Publication status	Published - 30 Jun 2003

Keywords

paramagnetic resonance
electronic-strucutre
adducts
triiodide
chains

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10.1021/ic034092f

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title = "Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex",

abstract = "The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented 'double' charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.",

keywords = "paramagnetic resonance, electronic-strucutre, adducts, triiodide, chains",

author = "D.W. Allen and R. Berridge and N. Bricklebank and S.D. Forder and F. Palacio and S.J. Coles and M.B. Hursthouse and P.J. Skabara",

year = "2003",

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language = "English",

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TY - JOUR

T1 - Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex

AU - Allen, D.W.

AU - Berridge, R.

AU - Bricklebank, N.

AU - Forder, S.D.

AU - Palacio, F.

AU - Coles, S.J.

AU - Hursthouse, M.B.

AU - Skabara, P.J.

PY - 2003/6/30

Y1 - 2003/6/30

N2 - The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented 'double' charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

AB - The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented 'double' charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

KW - paramagnetic resonance

KW - electronic-strucutre

KW - adducts

KW - triiodide

KW - chains

UR - http://pubs.acs.org/cgi-bin/article.cgi/inocaj/2003/42/i13/pdf/ic034092f.pdf

UR - http://dx.doi.org/10.1021/ic034092f

U2 - 10.1021/ic034092f

DO - 10.1021/ic034092f

M3 - Article

SN - 0020-1669

VL - 42

SP - 3975

EP - 3977

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex

Abstract

Keywords

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