Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex

D.W. Allen, R. Berridge, N. Bricklebank, S.D. Forder, F. Palacio, S.J. Coles, M.B. Hursthouse, P.J. Skabara

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented 'double' charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.
LanguageEnglish
Pages3975-3977
Number of pages2
JournalInorganic Chemistry
Volume42
Issue number13
DOIs
Publication statusPublished - 30 Jun 2003

Fingerprint

Thiones
Charge transfer
Structural properties
Magnetic properties
charge transfer
magnetic properties
ferrocenium

Keywords

  • paramagnetic resonance
  • electronic-strucutre
  • adducts
  • triiodide
  • chains

Cite this

Allen, D. W., Berridge, R., Bricklebank, N., Forder, S. D., Palacio, F., Coles, S. J., ... Skabara, P. J. (2003). Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex. Inorganic Chemistry, 42(13), 3975-3977. https://doi.org/10.1021/ic034092f
Allen, D.W. ; Berridge, R. ; Bricklebank, N. ; Forder, S.D. ; Palacio, F. ; Coles, S.J. ; Hursthouse, M.B. ; Skabara, P.J. / Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex. In: Inorganic Chemistry. 2003 ; Vol. 42, No. 13. pp. 3975-3977.
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Allen, DW, Berridge, R, Bricklebank, N, Forder, SD, Palacio, F, Coles, SJ, Hursthouse, MB & Skabara, PJ 2003, 'Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex' Inorganic Chemistry, vol. 42, no. 13, pp. 3975-3977. https://doi.org/10.1021/ic034092f

Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex. / Allen, D.W.; Berridge, R.; Bricklebank, N.; Forder, S.D.; Palacio, F.; Coles, S.J.; Hursthouse, M.B.; Skabara, P.J.

In: Inorganic Chemistry, Vol. 42, No. 13, 30.06.2003, p. 3975-3977.

Research output: Contribution to journalArticle

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T1 - Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex

AU - Allen, D.W.

AU - Berridge, R.

AU - Bricklebank, N.

AU - Forder, S.D.

AU - Palacio, F.

AU - Coles, S.J.

AU - Hursthouse, M.B.

AU - Skabara, P.J.

PY - 2003/6/30

Y1 - 2003/6/30

N2 - The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented 'double' charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

AB - The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented 'double' charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

KW - paramagnetic resonance

KW - electronic-strucutre

KW - adducts

KW - triiodide

KW - chains

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UR - http://dx.doi.org/10.1021/ic034092f

U2 - 10.1021/ic034092f

DO - 10.1021/ic034092f

M3 - Article

VL - 42

SP - 3975

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JO - Inorganic Chemistry

T2 - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

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Allen DW, Berridge R, Bricklebank N, Forder SD, Palacio F, Coles SJ et al. Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex. Inorganic Chemistry. 2003 Jun 30;42(13):3975-3977. https://doi.org/10.1021/ic034092f