Strategies towards chemoselective suzuki-miyaura cross-coupling

James W. B. Fyfe, Allan J. B. Watson

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Chemoselective Suzuki-Miyaura cross-coupling has emerged as a powerful method for the rapid preparation of sp2-and sp3-hybridized carbon frameworks based on control of the oxidative addition or transmetallation events. The field of chemoselective transmetallation has recently seen considerable development with several different strategies emerging including protected boronic acids, neighboring group activation, and chemoselective speciation. Herein, these state-of-the-art approaches towards chemoselective Suzuki-Miyaura cross-coupling are highlighted.
LanguageEnglish
Pages1139-1144
Number of pages6
JournalSynlett
Volume26
Issue number9
DOIs
Publication statusPublished - Jun 2015

Fingerprint

Boronic Acids
Carbon
Chemical activation

Keywords

  • boron
  • catalysis
  • chemoselectivity
  • cross-coupling
  • palladium

Cite this

Fyfe, James W. B. ; Watson, Allan J. B. / Strategies towards chemoselective suzuki-miyaura cross-coupling. In: Synlett. 2015 ; Vol. 26, No. 9. pp. 1139-1144.
@article{31f0c84e59d542b38e35cc14e857bd92,
title = "Strategies towards chemoselective suzuki-miyaura cross-coupling",
abstract = "Chemoselective Suzuki-Miyaura cross-coupling has emerged as a powerful method for the rapid preparation of sp2-and sp3-hybridized carbon frameworks based on control of the oxidative addition or transmetallation events. The field of chemoselective transmetallation has recently seen considerable development with several different strategies emerging including protected boronic acids, neighboring group activation, and chemoselective speciation. Herein, these state-of-the-art approaches towards chemoselective Suzuki-Miyaura cross-coupling are highlighted.",
keywords = "boron, catalysis, chemoselectivity, cross-coupling, palladium",
author = "Fyfe, {James W. B.} and Watson, {Allan J. B.}",
year = "2015",
month = "6",
doi = "10.1055/s-0034-1380324",
language = "English",
volume = "26",
pages = "1139--1144",
journal = "Synlett",
issn = "0936-5214",
number = "9",

}

Strategies towards chemoselective suzuki-miyaura cross-coupling. / Fyfe, James W. B.; Watson, Allan J. B.

In: Synlett, Vol. 26, No. 9, 06.2015, p. 1139-1144.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Strategies towards chemoselective suzuki-miyaura cross-coupling

AU - Fyfe, James W. B.

AU - Watson, Allan J. B.

PY - 2015/6

Y1 - 2015/6

N2 - Chemoselective Suzuki-Miyaura cross-coupling has emerged as a powerful method for the rapid preparation of sp2-and sp3-hybridized carbon frameworks based on control of the oxidative addition or transmetallation events. The field of chemoselective transmetallation has recently seen considerable development with several different strategies emerging including protected boronic acids, neighboring group activation, and chemoselective speciation. Herein, these state-of-the-art approaches towards chemoselective Suzuki-Miyaura cross-coupling are highlighted.

AB - Chemoselective Suzuki-Miyaura cross-coupling has emerged as a powerful method for the rapid preparation of sp2-and sp3-hybridized carbon frameworks based on control of the oxidative addition or transmetallation events. The field of chemoselective transmetallation has recently seen considerable development with several different strategies emerging including protected boronic acids, neighboring group activation, and chemoselective speciation. Herein, these state-of-the-art approaches towards chemoselective Suzuki-Miyaura cross-coupling are highlighted.

KW - boron

KW - catalysis

KW - chemoselectivity

KW - cross-coupling

KW - palladium

UR - https://www.thieme-connect.com/products/ejournals/journal/10.1055/s-00000083

U2 - 10.1055/s-0034-1380324

DO - 10.1055/s-0034-1380324

M3 - Article

VL - 26

SP - 1139

EP - 1144

JO - Synlett

T2 - Synlett

JF - Synlett

SN - 0936-5214

IS - 9

ER -