Strategies towards chemoselective suzuki-miyaura cross-coupling

James W. B. Fyfe, Allan J. B. Watson

Research output: Contribution to journalArticle

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Abstract

Chemoselective Suzuki-Miyaura cross-coupling has emerged as a powerful method for the rapid preparation of sp2-and sp3-hybridized carbon frameworks based on control of the oxidative addition or transmetallation events. The field of chemoselective transmetallation has recently seen considerable development with several different strategies emerging including protected boronic acids, neighboring group activation, and chemoselective speciation. Herein, these state-of-the-art approaches towards chemoselective Suzuki-Miyaura cross-coupling are highlighted.
Original languageEnglish
Pages (from-to)1139-1144
Number of pages6
JournalSynlett
Volume26
Issue number9
DOIs
Publication statusPublished - Jun 2015

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Keywords

  • boron
  • catalysis
  • chemoselectivity
  • cross-coupling
  • palladium

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