Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

Prokopis C. Andrikopoulos; David R. Armstrong; Eva Hevia; Alan R. Kennedy; Robert E. Mulvey; Charles T. O'Hara

doi:10.1039/b416636a

Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

Prokopis C. Andrikopoulos, David R. Armstrong, Eva Hevia, Alan R. Kennedy, Robert E. Mulvey, Charles T. O'Hara

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu42- dianions within a polycationic network, is reported.

Original language	English
Pages (from-to)	1131-1133
Number of pages	3
Journal	Chemical Communications (London)
Volume	2005
Issue number	9
Early online date	18 Jan 2005
DOIs	https://doi.org/10.1039/b416636a
Publication status	Published - Jan 2005

Keywords

magnesium
chemistry

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10.1039/b416636a

Cite this

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title = "Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions",

abstract = "Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu42- dianions within a polycationic network, is reported.",

keywords = "magnesium, chemistry",

author = "Andrikopoulos, {Prokopis C.} and Armstrong, {David R.} and Eva Hevia and Kennedy, {Alan R.} and Mulvey, {Robert E.} and O'Hara, {Charles T.}",

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language = "English",

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T1 - Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

AU - Andrikopoulos, Prokopis C.

AU - Armstrong, David R.

AU - Hevia, Eva

AU - Kennedy, Alan R.

AU - Mulvey, Robert E.

AU - O'Hara, Charles T.

PY - 2005/1

Y1 - 2005/1

N2 - Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu42- dianions within a polycationic network, is reported.

AB - Toluene is metallated by DABCO-activated disodium tetrabutylmagnesiate, but not by DABCO-activated monosodium tributylmagnesiate; this distinction is rationalised by DFT calculations on model systems, and the crystal structure of the main non-metallated product, which shows interstitial MgBu42- dianions within a polycationic network, is reported.

KW - magnesium

KW - chemistry

UR - http://www.rsc.org/ej/CC/2005/b416636a.pdf

U2 - 10.1039/b416636a

DO - 10.1039/b416636a

M3 - Article

VL - 2005

SP - 1131

EP - 1133

JO - Chemical Communications (London)

JF - Chemical Communications (London)

SN - 0009-241X

IS - 9

ER -

Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

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Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

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