Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines

R.E. Mulvey; Vasel Naseri; R.J. Less; Mary McPartlin; Dominic S. Wright

doi:10.1039/C0CC00827C

Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines

R.E. Mulvey, Vasel Naseri, R.J. Less, Mary McPartlin, Dominic S. Wright

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

The room-temperature reactions of stannocene, Cp*2Sn, with a range of primary phosphines, RPH2, result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*2SnCl2, however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.

Original language	English
Pages (from-to)	5000-5002
Number of pages	2
Journal	Chemical Communications (London)
Volume	46
Issue number	27
DOIs	https://doi.org/10.1039/C0CC00827C
Publication status	Published - 2010

Keywords

phosphines
dehydrocoupling
stannocene

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10.1039/C0CC00827C

Cite this

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abstract = "The room-temperature reactions of stannocene, Cp*2Sn, with a range of primary phosphines, RPH2, result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*2SnCl2, however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.",

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T1 - Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines

AU - Mulvey, R.E.

AU - Naseri, Vasel

AU - Less, R.J.

AU - McPartlin, Mary

AU - Wright, Dominic S.

PY - 2010

Y1 - 2010

N2 - The room-temperature reactions of stannocene, Cp*2Sn, with a range of primary phosphines, RPH2, result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*2SnCl2, however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.

AB - The room-temperature reactions of stannocene, Cp*2Sn, with a range of primary phosphines, RPH2, result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*2SnCl2, however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.

KW - phosphines

KW - dehydrocoupling

KW - stannocene

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UR - http://dx.doi.org/10.1039/C0CC00827C

U2 - 10.1039/C0CC00827C

DO - 10.1039/C0CC00827C

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Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines

Abstract

Keywords

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