Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines

R.E. Mulvey, Vasel Naseri, R.J. Less, Mary McPartlin, Dominic S. Wright

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

The room-temperature reactions of stannocene, Cp*2Sn, with a range of primary phosphines, RPH2, result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*2SnCl2, however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.
LanguageEnglish
Pages5000-5002
Number of pages2
JournalChemical Communications (London)
Volume46
Issue number27
DOIs
Publication statusPublished - 2010

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Phosphines
Metals
Temperature

Keywords

  • phosphines
  • dehydrocoupling
  • stannocene

Cite this

Mulvey, R.E. ; Naseri, Vasel ; Less, R.J. ; McPartlin, Mary ; Wright, Dominic S. / Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines. In: Chemical Communications (London). 2010 ; Vol. 46, No. 27. pp. 5000-5002.
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Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines. / Mulvey, R.E.; Naseri, Vasel; Less, R.J.; McPartlin, Mary; Wright, Dominic S.

In: Chemical Communications (London), Vol. 46, No. 27, 2010, p. 5000-5002.

Research output: Contribution to journalArticle

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AU - Wright, Dominic S.

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