Abstract
Structure-porosity relationships for metal-organic polyhedra (MOPs) are hardly investigated because they tend to be amorphized after activation, which inhibits crystallographic characterization. Here, we show a mixed-ligand strategy to statistically distribute two distinct carbazole-type ligands within rhodium-based octahedral MOPs, leading to systematic tuning of the microporosity in the resulting amorphous solids.
| Original language | English |
|---|---|
| Pages (from-to) | 6571-6575 |
| Number of pages | 5 |
| Journal | Inorganic Chemistry |
| Volume | 63 |
| Issue number | 15 |
| Early online date | 4 Apr 2024 |
| DOIs | |
| Publication status | Published - 15 Apr 2024 |
Funding
T.T. and J.T. are grateful to the Japan Society for the Promotion of Science (JSPS) for the postdoctoral fellowship. This work was supported by JSPS KAKENHI grant numbers JP22KJ1784 (JSPS Fellows) and JP23K13762 (Early-Career Scientists) for T.T. and JP23H00298 (Kiban A) for S.F. The authors thank the iCeMS Analysis Center for access to analytical instruments and Ms. Karin Nishimura (Kyoto University) for assistance in the mass spectrometry measurements.
Keywords
- metal-organic polyhedra
- porosity
- complexity
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