Statistical distribution of binary ligands within rhodium-organic octahedra tunes microporosity in their assemblies

Tomoki Tateishi; Javier Troyano; Shun Tokuda; Gavin A Craig; Simon Krause; Alfredo López-Olvera; Ilich A Ibarra; Shuhei Furukawa

doi:10.1021/acs.inorgchem.4c00964

Statistical distribution of binary ligands within rhodium-organic octahedra tunes microporosity in their assemblies

Tomoki Tateishi, Javier Troyano, Shun Tokuda, Gavin A Craig, Simon Krause, Alfredo López-Olvera, Ilich A Ibarra, Shuhei Furukawa

Pure And Applied Chemistry

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Abstract

Structure-porosity relationships for metal-organic polyhedra (MOPs) are hardly investigated because they tend to be amorphized after activation, which inhibits crystallographic characterization. Here, we show a mixed-ligand strategy to statistically distribute two distinct carbazole-type ligands within rhodium-based octahedral MOPs, leading to systematic tuning of the microporosity in the resulting amorphous solids.

Original language	English
Pages (from-to)	6571-6575
Number of pages	5
Journal	Inorganic Chemistry
Volume	63
Issue number	15
Early online date	4 Apr 2024
DOIs	https://doi.org/10.1021/acs.inorgchem.4c00964
Publication status	Published - 15 Apr 2024

Keywords

metal-organic polyhedra
porosity
complexity

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10.1021/acs.inorgchem.4c00964

statistical-distribution-of-binary-ligands-within-rhodium-organic-octahedra-tunes-microporosity-in-their-assembliesSubmitted manuscript, 1.11 MBLicence: CC BY-NC 4.0

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abstract = "Structure-porosity relationships for metal-organic polyhedra (MOPs) are hardly investigated because they tend to be amorphized after activation, which inhibits crystallographic characterization. Here, we show a mixed-ligand strategy to statistically distribute two distinct carbazole-type ligands within rhodium-based octahedral MOPs, leading to systematic tuning of the microporosity in the resulting amorphous solids.",

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author = "Tomoki Tateishi and Javier Troyano and Shun Tokuda and Craig, {Gavin A} and Simon Krause and Alfredo L{\'o}pez-Olvera and Ibarra, {Ilich A} and Shuhei Furukawa",

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T1 - Statistical distribution of binary ligands within rhodium-organic octahedra tunes microporosity in their assemblies

AU - Tateishi, Tomoki

AU - Troyano, Javier

AU - Tokuda, Shun

AU - Craig, Gavin A

AU - Krause, Simon

AU - López-Olvera, Alfredo

AU - Ibarra, Ilich A

AU - Furukawa, Shuhei

PY - 2024/4/15

Y1 - 2024/4/15

N2 - Structure-porosity relationships for metal-organic polyhedra (MOPs) are hardly investigated because they tend to be amorphized after activation, which inhibits crystallographic characterization. Here, we show a mixed-ligand strategy to statistically distribute two distinct carbazole-type ligands within rhodium-based octahedral MOPs, leading to systematic tuning of the microporosity in the resulting amorphous solids.

AB - Structure-porosity relationships for metal-organic polyhedra (MOPs) are hardly investigated because they tend to be amorphized after activation, which inhibits crystallographic characterization. Here, we show a mixed-ligand strategy to statistically distribute two distinct carbazole-type ligands within rhodium-based octahedral MOPs, leading to systematic tuning of the microporosity in the resulting amorphous solids.

KW - metal-organic polyhedra

KW - porosity

KW - complexity

U2 - 10.1021/acs.inorgchem.4c00964

DO - 10.1021/acs.inorgchem.4c00964

M3 - Article

C2 - 38572833

SN - 0020-1669

VL - 63

SP - 6571

EP - 6575

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 15

ER -

Statistical distribution of binary ligands within rhodium-organic octahedra tunes microporosity in their assemblies

Abstract

Keywords

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