Star-shaped π-conjugated oligomers and their applications in organic electronics and photonics

Alexander L. Kanibolotsky, Igor F. Perepichka, Peter J. Skabara

Research output: Contribution to journalArticlepeer-review

289 Citations (Scopus)
218 Downloads (Pure)


Abstract: Strategies for the design and construction of non-linear, 2D and 3D conjugated macromolecules are presented in this critical review. The materials, termed here as star-shaped structures, feature a core unit which may or may not provide conjugated links between arms that radiate like spokes from a central axle. The arms of the macromolecules consist of linear oligomers or irregular conjugated chains lacking a formal repeat unit. The cores range from simple atoms to single or fused aromatic units and can provide a high level of symmetry to the overall structure. The physical properties of the star-shaped materials can be markedly different to their simple, linear conjugated analogues. These differences are highlighted and we report on anomalies in absorption/emission characteristics, electronic energy levels, thermal properties and morphology of thin films. We provide numerous examples for the application of star-shaped conjugated macromolecules in organic semiconductor devices; a comparison of their device performance with those comprising analogous linear systems provides clear evidence that the star-shaped compounds are an important class of material in organic electronics. Moreover, these structures are monodisperse, well-defined, discrete molecules with 100% synthetic reproducibility, and possess high purity and excellent solubility in common organic solvents. They feature many of the attributes of plastic materials (good film-forming properties, thermal stability, flexibility) and are therefore extremely attractive alternatives to conjugated polymers.
Original languageEnglish
Pages (from-to)2695-2728
Number of pages34
JournalChemical Society Reviews
Issue number7
Early online date2 Jun 2010
Publication statusPublished - 1 Jul 2010


  • conjugated oligomers
  • photonics
  • organic electronics


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