Spectroelectrochemistry of poly(ethylenedithiathiophene) - the sulfur analogue of poly(ethylenedioxythiophene)

A. Cravino, H. Neugebauer, A. Petr, P.J. Skabara, H.J. Spencer, J.J.W. McDouall, L. Dunsch, N.S. Sariciftci

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26 Citations (Scopus)

Abstract

Poly(3,4-ethylenedithiathiophene) (PEDTT) is a polythiophene-like conjugated polymer in which each thiophene ring is functionalized with an ethylenedithia bridge. As such, PEDTT is the sulfur analogue of the well-known poly(3,4-ethylenedioxythiophene) (PEDOT). Substituent effects, namely the presence of sulfur atoms in PEDTT replacing the oxygen atoms of PEDOT, do not provide a simple explanation for the different electronic properties of the two polymers in the neutral state. This paper reports the spectroscopic properties of PEDTT, studied by in situ techniques such as IR-, Vis-, and electron spin resonance (ESR) spectroelectrochemistry. The differences observed upon electrochemical oxidation of PEDTT and PEDOT (e.g., the different infrared active vibrational band patterns in IR spectroelectrochemistry as well as the different nature of the charged states) are even more marked than those observed in the neutral state. These results, with AMI calculations, indicate conformational effects as a possible explanation for the different electronic and spectroscopic properties of PEDTT and PEDOT.
Original languageEnglish
Pages (from-to)2662-2667
Number of pages5
JournalJournal of Physical Chemistry B
Volume110
Issue number6
DOIs
Publication statusPublished - 16 Feb 2006

Keywords

  • in-situ FTIR
  • conjugated polymers
  • poly(3
  • 4-ethylenedioxythiophene) films
  • vibrational spectroscopy
  • infrared activity
  • 4-ethylenedithiathiophene)
  • electropolymerization
  • systems
  • states
  • raman

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    Cravino, A., Neugebauer, H., Petr, A., Skabara, P. J., Spencer, H. J., McDouall, J. J. W., ... Sariciftci, N. S. (2006). Spectroelectrochemistry of poly(ethylenedithiathiophene) - the sulfur analogue of poly(ethylenedioxythiophene). Journal of Physical Chemistry B, 110(6), 2662-2667. https://doi.org/10.1021/jp0562173