Some factors influencing exfoliation and physical property enhancement in nanoclay epoxy resins based on diglycidyl ethers of bisphenol A and F

S.E. Ingram, I. Rhoney, J.J. Liggat, N.E. Hudson, R.A. Pethrick

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

An investigation of the factors influencing the degree of exfoliation of an organically modified clay in a series of epoxy resins is reported. The use of sonication, choice of curing agent, effect of the moisture content of the clay, and the cure temperature were examined. The dispersion was characterized using a combination of rheological measurements, X-ray diffraction, and dynamic mechanical thermal analysis. Rheological analysis of the clay dispersion in the epoxy monomer indicated that at high clay loads Herschel-Bulkley type behavior is followed. Higher cure temperatures and higher levels of clay moisture were found to influence the extent of exfoliation. Improvements in physical properties were observed through the addition of nanocomposites. The DGEBA/DDM and DEGEBA/DDS exhibited 2 and 4°C increase, respectively, in Tg per wt % of added clay. DGEBF showed virtually no enhancement.
Original languageEnglish
Pages (from-to)5-19
Number of pages14
JournalJournal of Applied Polymer Science
Volume106
Issue number1
DOIs
Publication statusPublished - 5 Oct 2007

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Epoxy Resins
Epoxy resins
Ethers
Clay
Physical properties
Moisture
Sonication
Thermoanalysis
Curing
clay
2,2-bis(4-glycidyloxyphenyl)propane
bisphenol F diglycidyl ether
Nanocomposites
Monomers
X ray diffraction
Temperature

Keywords

  • epoxy
  • nanocomposites
  • montmorillonite clay
  • exfoliation
  • nanoclay epoxy resin

Cite this

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title = "Some factors influencing exfoliation and physical property enhancement in nanoclay epoxy resins based on diglycidyl ethers of bisphenol A and F",
abstract = "An investigation of the factors influencing the degree of exfoliation of an organically modified clay in a series of epoxy resins is reported. The use of sonication, choice of curing agent, effect of the moisture content of the clay, and the cure temperature were examined. The dispersion was characterized using a combination of rheological measurements, X-ray diffraction, and dynamic mechanical thermal analysis. Rheological analysis of the clay dispersion in the epoxy monomer indicated that at high clay loads Herschel-Bulkley type behavior is followed. Higher cure temperatures and higher levels of clay moisture were found to influence the extent of exfoliation. Improvements in physical properties were observed through the addition of nanocomposites. The DGEBA/DDM and DEGEBA/DDS exhibited 2 and 4°C increase, respectively, in Tg per wt {\%} of added clay. DGEBF showed virtually no enhancement.",
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Some factors influencing exfoliation and physical property enhancement in nanoclay epoxy resins based on diglycidyl ethers of bisphenol A and F. / Ingram, S.E.; Rhoney, I.; Liggat, J.J.; Hudson, N.E.; Pethrick, R.A.

In: Journal of Applied Polymer Science, Vol. 106, No. 1, 05.10.2007, p. 5-19.

Research output: Contribution to journalArticle

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T1 - Some factors influencing exfoliation and physical property enhancement in nanoclay epoxy resins based on diglycidyl ethers of bisphenol A and F

AU - Ingram, S.E.

AU - Rhoney, I.

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AU - Hudson, N.E.

AU - Pethrick, R.A.

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AB - An investigation of the factors influencing the degree of exfoliation of an organically modified clay in a series of epoxy resins is reported. The use of sonication, choice of curing agent, effect of the moisture content of the clay, and the cure temperature were examined. The dispersion was characterized using a combination of rheological measurements, X-ray diffraction, and dynamic mechanical thermal analysis. Rheological analysis of the clay dispersion in the epoxy monomer indicated that at high clay loads Herschel-Bulkley type behavior is followed. Higher cure temperatures and higher levels of clay moisture were found to influence the extent of exfoliation. Improvements in physical properties were observed through the addition of nanocomposites. The DGEBA/DDM and DEGEBA/DDS exhibited 2 and 4°C increase, respectively, in Tg per wt % of added clay. DGEBF showed virtually no enhancement.

KW - epoxy

KW - nanocomposites

KW - montmorillonite clay

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KW - nanoclay epoxy resin

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