Abstract
Initiation rates for Grubbs and Grubbs-Hoveyda second generation pre-catalysts have been measured accurately in a range of solvents. Solvatochromic fitting reveals different dependencies on key solvent parameters for the two pre-catalysts, consistent with different mechanisms by which the Grubbs and Grubbs-Hoveyda pre-catalysts initiate.
| Original language | English |
|---|---|
| Pages (from-to) | 4110-4113 |
| Number of pages | 4 |
| Journal | Dalton Transactions |
| Volume | 42 |
| Issue number | 12 |
| Early online date | 13 Nov 2012 |
| DOIs | |
| Publication status | Published - 2013 |
Keywords
- Grubbs–Hoveyda
- pre-catalysts
- solvent effects
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