Solvent effects on Grubbs’ pre-catalyst initiation rates

Ian W. Ashworth, David Nelson, Jonathan Percy

Research output: Contribution to journalArticle

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Abstract

Initiation rates for Grubbs and Grubbs-Hoveyda second generation pre-catalysts have been measured accurately in a range of solvents. Solvatochromic fitting reveals different dependencies on key solvent parameters for the two pre-catalysts, consistent with different mechanisms by which the Grubbs and Grubbs-Hoveyda pre-catalysts initiate.
Original languageEnglish
Pages (from-to)4110-4113
Number of pages4
JournalDalton Transactions
Volume42
Issue number12
Early online date13 Nov 2012
DOIs
Publication statusPublished - 2013

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Keywords

  • Grubbs–Hoveyda
  • pre-catalysts
  • solvent effects

Cite this

Ashworth, Ian W. ; Nelson, David ; Percy, Jonathan. / Solvent effects on Grubbs’ pre-catalyst initiation rates. In: Dalton Transactions. 2013 ; Vol. 42, No. 12. pp. 4110-4113.
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Solvent effects on Grubbs’ pre-catalyst initiation rates. / Ashworth, Ian W.; Nelson, David; Percy, Jonathan.

In: Dalton Transactions, Vol. 42, No. 12, 2013, p. 4110-4113.

Research output: Contribution to journalArticle

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