Solubility of glucose in mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water

P. Tsavas; S. Polydorou; I. Faflia; E.C. Voutsas; D. Tassios; M.V. Flores; K. Naraghi; P.J. Halling; F. Chamouleau; M. Ghoul; J.M. Engasser; M. Ferrer; F.J. Plou

doi:10.1021/je0102457

Solubility of glucose in mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water

P. Tsavas, S. Polydorou, I. Faflia, E.C. Voutsas, D. Tassios, M.V. Flores, K. Naraghi, P.J. Halling, F. Chamouleau, M. Ghoul, J.M. Engasser, M. Ferrer, F.J. Plou

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Solubility measurements of glucose in a variety of binary, ternary, and multicomponent mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water at different temperatures are presented. The solubilities of crystalline beta-glucose, amorphous beta-glucose, and amorphous beta-glucose in 2-methyl-2-butanol at 60 degreesC have also been measured. The results show that the solubilities of the amorphous forms in 2-methyl-2-butanol are higher than that of the corresponding crystalline form. The presence of dimethyl sulfoxide significantly increases glucose solubility in 2- methyl-2-butanol. Finally, the presence of glucose ester increases glucose solubility in 2-methyl-2-butanol, while the presence of fatty acid has the opposite effect.

Original language	English
Pages (from-to)	807-810
Number of pages	3
Journal	Journal of Chemical and Engineering Data
Volume	47
Issue number	4
DOIs	https://doi.org/10.1021/je0102457
Publication status	Published - Jul 2002

Keywords

Lipase
fructose

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10.1021/je0102457

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Tsavas, P., Polydorou, S., Faflia, I., Voutsas, E. C., Tassios, D., Flores, M. V., Naraghi, K., Halling, P. J., Chamouleau, F., Ghoul, M., Engasser, J. M., Ferrer, M., & Plou, F. J. (2002). Solubility of glucose in mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water. Journal of Chemical and Engineering Data, 47(4), 807-810. https://doi.org/10.1021/je0102457

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title = "Solubility of glucose in mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water",

abstract = "Solubility measurements of glucose in a variety of binary, ternary, and multicomponent mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water at different temperatures are presented. The solubilities of crystalline beta-glucose, amorphous beta-glucose, and amorphous beta-glucose in 2-methyl-2-butanol at 60 degreesC have also been measured. The results show that the solubilities of the amorphous forms in 2-methyl-2-butanol are higher than that of the corresponding crystalline form. The presence of dimethyl sulfoxide significantly increases glucose solubility in 2- methyl-2-butanol. Finally, the presence of glucose ester increases glucose solubility in 2-methyl-2-butanol, while the presence of fatty acid has the opposite effect.",

keywords = "Lipase, fructose",

author = "P. Tsavas and S. Polydorou and I. Faflia and E.C. Voutsas and D. Tassios and M.V. Flores and K. Naraghi and P.J. Halling and F. Chamouleau and M. Ghoul and J.M. Engasser and M. Ferrer and F.J. Plou",

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doi = "10.1021/je0102457",

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Tsavas, P, Polydorou, S, Faflia, I, Voutsas, EC, Tassios, D, Flores, MV, Naraghi, K, Halling, PJ, Chamouleau, F, Ghoul, M, Engasser, JM, Ferrer, M & Plou, FJ 2002, 'Solubility of glucose in mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water', Journal of Chemical and Engineering Data, vol. 47, no. 4, pp. 807-810. https://doi.org/10.1021/je0102457

TY - JOUR

T1 - Solubility of glucose in mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water

AU - Tsavas, P.

AU - Polydorou, S.

AU - Faflia, I.

AU - Voutsas, E.C.

AU - Tassios, D.

AU - Flores, M.V.

AU - Naraghi, K.

AU - Halling, P.J.

AU - Chamouleau, F.

AU - Ghoul, M.

AU - Engasser, J.M.

AU - Ferrer, M.

AU - Plou, F.J.

PY - 2002/7

Y1 - 2002/7

N2 - Solubility measurements of glucose in a variety of binary, ternary, and multicomponent mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water at different temperatures are presented. The solubilities of crystalline beta-glucose, amorphous beta-glucose, and amorphous beta-glucose in 2-methyl-2-butanol at 60 degreesC have also been measured. The results show that the solubilities of the amorphous forms in 2-methyl-2-butanol are higher than that of the corresponding crystalline form. The presence of dimethyl sulfoxide significantly increases glucose solubility in 2- methyl-2-butanol. Finally, the presence of glucose ester increases glucose solubility in 2-methyl-2-butanol, while the presence of fatty acid has the opposite effect.

AB - Solubility measurements of glucose in a variety of binary, ternary, and multicomponent mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water at different temperatures are presented. The solubilities of crystalline beta-glucose, amorphous beta-glucose, and amorphous beta-glucose in 2-methyl-2-butanol at 60 degreesC have also been measured. The results show that the solubilities of the amorphous forms in 2-methyl-2-butanol are higher than that of the corresponding crystalline form. The presence of dimethyl sulfoxide significantly increases glucose solubility in 2- methyl-2-butanol. Finally, the presence of glucose ester increases glucose solubility in 2-methyl-2-butanol, while the presence of fatty acid has the opposite effect.

KW - Lipase

KW - fructose

UR - http://pubs.acs.org/cgi-bin/article.cgi/jceaax/2002/47/i04/pdf/je0102457.pdf

UR - http://dx.doi.org/10.1021/je0102457

U2 - 10.1021/je0102457

DO - 10.1021/je0102457

M3 - Article

SN - 0021-9568

VL - 47

SP - 807

EP - 810

JO - Journal of Chemical and Engineering Data

JF - Journal of Chemical and Engineering Data

IS - 4

ER -

Solubility of glucose in mixtures containing 2-methyl-2- butanol, dimethyl sulfoxide, acids, esters, and water

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