Soft Scorpionate anions as platforms for novel heterocycles

Rajeev Rajasekharan Nair, Annemarie Marckwordt, Samuel Lutta, Matthias Schwalbe, Anne Biernat, David Armstrong, Allan Watson, Alan Kennedy, John Reglinski, Mark Spicer

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Soft scorpionates have thus far been seen mainly as a family of ligands. Their chemistry is extended here to the production of novel cationic macrocycles using dihaloalkanes. By replacing the dihaloalkanes with mild oxidising agents (NO+, I2) we obtain two unique polycyclic heterocycles. The mechanism which leads to the formation of these polycyclic heterocycles is investigated using ab-initio DFT calculations.
Original languageEnglish
Pages (from-to)13561–13568
JournalChemistry - A European Journal
Volume19
Issue number40
DOIs
Publication statusPublished - 2013

Keywords

  • soft scorpionates
  • ligands
  • heterocycles

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