Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

M. Garner, M.A. Lehmann, J. Reglinski, M.D. Spicer

Research output: Contribution to journalArticle

Abstract

The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.
Original languageEnglish
Pages (from-to)5233-5236
Number of pages3
JournalOrganometallics
Volume20
Issue number24
DOIs
Publication statusPublished - 26 Nov 2001

Keywords

  • CRYSTAL-STRUCTURE
  • TRIPODAL LIGANDS
  • ZINC
  • HYDROTRIS(METHIMAZOLYL)BORATE
  • HYDROTRIS(PYRAZOLYL)BORATE
  • LITHIUM
  • IONS
  • HARD

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    Garner, M., Lehmann, M. A., Reglinski, J., & Spicer, M. D. (2001). Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls. Organometallics, 20(24), 5233-5236. https://doi.org/10.1021/om010559n