Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

M. Garner; M.A. Lehmann; J. Reglinski; M.D. Spicer

doi:10.1021/om010559n

Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

M. Garner, M.A. Lehmann, J. Reglinski, M.D. Spicer

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.

Original language	English
Pages (from-to)	5233-5236
Number of pages	3
Journal	Organometallics
Volume	20
Issue number	24
DOIs	https://doi.org/10.1021/om010559n
Publication status	Published - 26 Nov 2001

Keywords

CRYSTAL-STRUCTURE
TRIPODAL LIGANDS
ZINC
HYDROTRIS(METHIMAZOLYL)BORATE
HYDROTRIS(PYRAZOLYL)BORATE
LITHIUM
IONS
HARD

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title = "Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls",

abstract = "The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.",

keywords = "CRYSTAL-STRUCTURE, TRIPODAL LIGANDS, ZINC, HYDROTRIS(METHIMAZOLYL)BORATE, HYDROTRIS(PYRAZOLYL)BORATE, LITHIUM, IONS, HARD",

author = "M. Garner and M.A. Lehmann and J. Reglinski and M.D. Spicer",

year = "2001",

month = nov,

day = "26",

doi = "10.1021/om010559n",

language = "English",

volume = "20",

pages = "5233--5236",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "24",

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TY - JOUR

T1 - Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

AU - Garner, M.

AU - Lehmann, M.A.

AU - Reglinski, J.

AU - Spicer, M.D.

PY - 2001/11/26

Y1 - 2001/11/26

N2 - The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.

AB - The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.

KW - CRYSTAL-STRUCTURE

KW - TRIPODAL LIGANDS

KW - ZINC

KW - HYDROTRIS(METHIMAZOLYL)BORATE

KW - HYDROTRIS(PYRAZOLYL)BORATE

KW - LITHIUM

KW - IONS

KW - HARD

UR - http://pubs.acs.org/cgi-bin/article.cgi/orgnd7/2001/20/i24/pdf/om010559n.pdf

UR - http://dx.doi.org/10.1021/om010559n

U2 - 10.1021/om010559n

DO - 10.1021/om010559n

M3 - Article

SN - 0276-7333

VL - 20

SP - 5233

EP - 5236

JO - Organometallics

JF - Organometallics

IS - 24

ER -

Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

Abstract

Keywords

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