Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

M. Garner, M.A. Lehmann, J. Reglinski, M.D. Spicer

Research output: Contribution to journalArticle

Abstract

The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.
Original languageEnglish
Pages (from-to)5233-5236
Number of pages3
JournalOrganometallics
Volume20
Issue number24
DOIs
Publication statusPublished - 26 Nov 2001

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Tungsten
Molybdenum
Organometallics
borates
entry
molybdenum
tungsten
transition metals
Borates
ligands
crystal structure
predictions
Transition metals
Crystal structure
Ligands

Keywords

  • CRYSTAL-STRUCTURE
  • TRIPODAL LIGANDS
  • ZINC
  • HYDROTRIS(METHIMAZOLYL)BORATE
  • HYDROTRIS(PYRAZOLYL)BORATE
  • LITHIUM
  • IONS
  • HARD

Cite this

Garner, M., Lehmann, M. A., Reglinski, J., & Spicer, M. D. (2001). Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls. Organometallics, 20(24), 5233-5236. https://doi.org/10.1021/om010559n
Garner, M. ; Lehmann, M.A. ; Reglinski, J. ; Spicer, M.D. / Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls. In: Organometallics. 2001 ; Vol. 20, No. 24. pp. 5233-5236.
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Garner, M, Lehmann, MA, Reglinski, J & Spicer, MD 2001, 'Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls', Organometallics, vol. 20, no. 24, pp. 5233-5236. https://doi.org/10.1021/om010559n

Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls. / Garner, M.; Lehmann, M.A.; Reglinski, J.; Spicer, M.D.

In: Organometallics, Vol. 20, No. 24, 26.11.2001, p. 5233-5236.

Research output: Contribution to journalArticle

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T1 - Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

AU - Garner, M.

AU - Lehmann, M.A.

AU - Reglinski, J.

AU - Spicer, M.D.

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N2 - The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.

AB - The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.

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KW - TRIPODAL LIGANDS

KW - ZINC

KW - HYDROTRIS(METHIMAZOLYL)BORATE

KW - HYDROTRIS(PYRAZOLYL)BORATE

KW - LITHIUM

KW - IONS

KW - HARD

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