Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex

L.M. Carrella, William Clegg, D.V. Graham, L.M. Hogg, A.R. Kennedy, J. Klett, R.E. Mulvey, E. Rentschler

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6-tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic.
LanguageEnglish
Pages4662-4666
Number of pages4
JournalAngewandte Chemie
Volume46
Issue number25
DOIs
Publication statusPublished - 2007

Fingerprint

Benzene
Crowns
Metals
Sodium
X-Rays
Temperature
2,2,6,6-tetramethylpiperidide

Keywords

  • alkali metals
  • arenes
  • inverse-crown compounds
  • manganese
  • metalation

Cite this

Carrella, L.M. ; Clegg, William ; Graham, D.V. ; Hogg, L.M. ; Kennedy, A.R. ; Klett, J. ; Mulvey, R.E. ; Rentschler, E. / Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex. In: Angewandte Chemie. 2007 ; Vol. 46, No. 25. pp. 4662-4666.
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Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex. / Carrella, L.M.; Clegg, William; Graham, D.V.; Hogg, L.M.; Kennedy, A.R.; Klett, J.; Mulvey, R.E.; Rentschler, E.

In: Angewandte Chemie, Vol. 46, No. 25, 2007, p. 4662-4666.

Research output: Contribution to journalArticle

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