Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex

L.M. Carrella; William Clegg; D.V. Graham; L.M. Hogg; A.R. Kennedy; J. Klett; R.E. Mulvey; E. Rentschler

doi:10.1002/anie.200700965

Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex

L.M. Carrella, William Clegg, D.V. Graham, L.M. Hogg, A.R. Kennedy, J. Klett, R.E. Mulvey, E. Rentschler

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6-tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic.

Original language	English
Pages (from-to)	4662-4666
Number of pages	4
Journal	Angewandte Chemie
Volume	46
Issue number	25
DOIs	https://doi.org/10.1002/anie.200700965
Publication status	Published - 2007

Keywords

alkali metals
arenes
inverse-crown compounds
manganese
metalation

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10.1002/anie.200700965

Cite this

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title = "Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex",

abstract = "Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6-tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic.",

keywords = "alkali metals, arenes, inverse-crown compounds, manganese, metalation",

author = "L.M. Carrella and William Clegg and D.V. Graham and L.M. Hogg and A.R. Kennedy and J. Klett and R.E. Mulvey and E. Rentschler",

note = "Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record.",

year = "2007",

doi = "10.1002/anie.200700965",

language = "English",

volume = "46",

pages = "4662--4666",

journal = "Angewandte Chemie",

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publisher = "John Wiley and Sons Ltd",

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T1 - Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex

AU - Carrella, L.M.

AU - Clegg, William

AU - Graham, D.V.

AU - Hogg, L.M.

AU - Kennedy, A.R.

AU - Klett, J.

AU - Mulvey, R.E.

AU - Rentschler, E.

N1 - Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record.

PY - 2007

Y1 - 2007

N2 - Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6-tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic.

AB - Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6-tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic.

KW - alkali metals

KW - arenes

KW - inverse-crown compounds

KW - manganese

KW - metalation

UR - http://dx.doi.org/10.1002/anie.200700965

U2 - 10.1002/anie.200700965

DO - 10.1002/anie.200700965

M3 - Article

SN - 0044-8249

VL - 46

SP - 4662

EP - 4666

JO - Angewandte Chemie

JF - Angewandte Chemie

IS - 25

ER -

Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex

Abstract

Keywords

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"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY

x-ray diffractometer

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Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex

Abstract

Keywords

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"INVERSE" COORDINATION: A NEW DESIGN CONCEPT IN SUPRAMOLECULAR INORGANIC CHEMISTRY

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x-ray diffractometer

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