Smouldering to treat PFAS in sewage sludge

T Fournie, T L Rashwan, C Switzer, J I Gerhard

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

Wastewater treatment plants are accumulation points for per- and polyfluoroalkyl substances (PFAS), and are threfore important facilities for PFAS treatment. This study explored using smouldering combustion to treat PFAS in sewage sludge. Base case experiments at the laboratory scale (LAB) used dried sludge mixed with sand. High moisture content (MC) LAB tests, 75% MC sludge by mass, explored impacts of MC on treatment and supplemented with granular activated carbon (GAC) to achieve sufficient temperatures for thermal destruction of PFAS. Additional LAB tests explored using calcium oxide (CaO) to support fluorine mineralization. Further tests performed at an oil-drum scale (DRUM) assessed scale on PFAS removal. Pre-treatment sludge and post-treatment ash samples from all tests were analyzed for 12 PFAS (2C–8C). Additional emissions samples were collected from all LAB tests and analyzed for 12 PFAS and hydrogen fluoride.

Smouldering removed all monitored PFAS from DRUM tests, and 4–8 carbon chain length PFAS from LAB tests. For base case tests, PFOS and PFOA were completely removed from sludge; however, high contents in the emissions (79–94% of total PFAS by mass) showed volatilization without degradation. Smouldering high MC sludge at ∼ 900 °C (30 g GAC/kg sand) improved PFAS degradation compared to treatment below 800 °C (
Original languageEnglish
Pages (from-to)219-227
Number of pages9
JournalWaste management
Volume164
Early online date19 Apr 2023
DOIs
Publication statusPublished - 1 Jun 2023

Keywords

  • Sewage
  • Charcoal
  • Smouldering combustion
  • PFAS
  • Sand
  • Fluorocarbons - analysis
  • Wastewater treatment
  • Fluorine
  • Incineration
  • Sewage sludge
  • Remediation

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