Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

Alexandra Collet; Gavin A. Craig; María José Heras Ojea; Lakshmi Bhaskaran; Claire Wilson; Stephen Hill; Mark Murrie

doi:10.1039/C8DT01997E

Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

Alexandra Collet, Gavin A. Craig, María José Heras Ojea, Lakshmi Bhaskaran, Claire Wilson, Stephen Hill, Mark Murrie

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Abstract

We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.

Original language	English
Pages (from-to)	9237-9240
Number of pages	4
Journal	Dalton Transactions
Volume	47
Issue number	28
DOIs	https://doi.org/10.1039/C8DT01997E
Publication status	Published - 18 Jun 2018

Keywords

slow magnetic relaxation
magnetic anisotropy
trigonal bipyramidal geometry

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10.1039/C8DT01997ELicence: CC BY 4.0

Collet-etal-DT2018-Slow-magnetic-relaxation-[CoIICoIII2]-complex-containing-high-magnetic-anisotropy-trigonal-bipyramidal-CoIIFinal published version, 784 KBLicence: CC BY 4.0

Cite this

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title = "Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre",

abstract = "We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.",

keywords = "slow magnetic relaxation, magnetic anisotropy, trigonal bipyramidal geometry",

author = "Alexandra Collet and Craig, {Gavin A.} and {Heras Ojea}, {Mar{\'i}a Jos{\'e}} and Lakshmi Bhaskaran and Claire Wilson and Stephen Hill and Mark Murrie",

year = "2018",

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doi = "10.1039/C8DT01997E",

language = "English",

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T1 - Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

AU - Collet, Alexandra

AU - Craig, Gavin A.

AU - Heras Ojea, María José

AU - Bhaskaran, Lakshmi

AU - Wilson, Claire

AU - Hill, Stephen

AU - Murrie, Mark

PY - 2018/6/18

Y1 - 2018/6/18

N2 - We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.

AB - We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.

KW - slow magnetic relaxation

KW - magnetic anisotropy

KW - trigonal bipyramidal geometry

U2 - 10.1039/C8DT01997E

DO - 10.1039/C8DT01997E

M3 - Article

SN - 1477-9226

VL - 47

SP - 9237

EP - 9240

JO - Dalton Transactions

JF - Dalton Transactions

IS - 28

ER -

Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

Abstract

Keywords

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