Six-coordinated Cd(II) centres as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine

Mark Spicer, L.R. Hanton, D.B. Cordes

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The networks for 2 and 3 were 4-fold interpenetrated and isotopological. The reaction of CdSO4 with bpaH+ led to the formation of a two-dimensional (2D) hydrogen-bonded net (4). Complex 4 consisted of discrete six-coordinate mononuclear units linked into a 2D network by a number of different hydrogen-bonding interactions. The topological analysis of this network showed it to be reminiscent of a 2D diagonal section of an α-polonium network.
LanguageEnglish
Pages328-336
Number of pages9
JournalCrystal Growth and Design
Volume7
DOIs
Publication statusPublished - 2007

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Polonium
coordination polymers
Amines
Hydrogen
Hydrogen bonds
amines
Polymers
polonium
hydrogen
interactions

Keywords

  • polymer networks
  • bis(4-pyridyl)amine
  • hydrogen-bonded net
  • α-polonium network

Cite this

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title = "Six-coordinated Cd(II) centres as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine",
abstract = "The networks for 2 and 3 were 4-fold interpenetrated and isotopological. The reaction of CdSO4 with bpaH+ led to the formation of a two-dimensional (2D) hydrogen-bonded net (4). Complex 4 consisted of discrete six-coordinate mononuclear units linked into a 2D network by a number of different hydrogen-bonding interactions. The topological analysis of this network showed it to be reminiscent of a 2D diagonal section of an α-polonium network.",
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language = "English",
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pages = "328--336",
journal = "Crystal Growth and Design",
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Six-coordinated Cd(II) centres as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine. / Spicer, Mark; Hanton, L.R.; Cordes, D.B.

In: Crystal Growth and Design, Vol. 7, 2007, p. 328-336.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Six-coordinated Cd(II) centres as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine

AU - Spicer, Mark

AU - Hanton, L.R.

AU - Cordes, D.B.

PY - 2007

Y1 - 2007

N2 - The networks for 2 and 3 were 4-fold interpenetrated and isotopological. The reaction of CdSO4 with bpaH+ led to the formation of a two-dimensional (2D) hydrogen-bonded net (4). Complex 4 consisted of discrete six-coordinate mononuclear units linked into a 2D network by a number of different hydrogen-bonding interactions. The topological analysis of this network showed it to be reminiscent of a 2D diagonal section of an α-polonium network.

AB - The networks for 2 and 3 were 4-fold interpenetrated and isotopological. The reaction of CdSO4 with bpaH+ led to the formation of a two-dimensional (2D) hydrogen-bonded net (4). Complex 4 consisted of discrete six-coordinate mononuclear units linked into a 2D network by a number of different hydrogen-bonding interactions. The topological analysis of this network showed it to be reminiscent of a 2D diagonal section of an α-polonium network.

KW - polymer networks

KW - bis(4-pyridyl)amine

KW - hydrogen-bonded net

KW - α-polonium network

U2 - 10.1021/cg0604632

DO - 10.1021/cg0604632

M3 - Article

VL - 7

SP - 328

EP - 336

JO - Crystal Growth and Design

T2 - Crystal Growth and Design

JF - Crystal Growth and Design

SN - 1528-7483

ER -