Six-coordinated Cd(II) centres as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine

Mark Spicer, L.R. Hanton, D.B. Cordes

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The networks for 2 and 3 were 4-fold interpenetrated and isotopological. The reaction of CdSO4 with bpaH+ led to the formation of a two-dimensional (2D) hydrogen-bonded net (4). Complex 4 consisted of discrete six-coordinate mononuclear units linked into a 2D network by a number of different hydrogen-bonding interactions. The topological analysis of this network showed it to be reminiscent of a 2D diagonal section of an α-polonium network.
Original languageEnglish
Pages (from-to)328-336
Number of pages9
JournalCrystal Growth and Design
Volume7
DOIs
Publication statusPublished - 2007

Keywords

  • polymer networks
  • bis(4-pyridyl)amine
  • hydrogen-bonded net
  • α-polonium network

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