Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone

D. R. Armstrong; L. Balloch; J. J. Crawford; B. J. Fleming; L. M. Hogg; A. R. Kennedy; J. Klett; R. E. Mulvey; C. T. O'Hara; S. A. Orr; Stuart Robertson

doi:10.1039/c1cc12869h

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone

D. R. Armstrong, L. Balloch, J. J. Crawford, B. J. Fleming, L. M. Hogg, A. R. Kennedy, J. Klett, R. E. Mulvey, C. T. O'Hara, S. A. Orr, Stuart Robertson

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

More usually thought of as a base, the sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)center dot Na(mu-TMP)-(mu-TEMPO )Zn(Bu-t)] 2 and [(TMEDA)center dot Na(mu-TEMPO )(2)-Zn(Bu-t)] 3; and with chalcone [PhCOCH=CHPh] gives [{(TMEDA)center dot Na(mu-TMP)Zn(Bu-t)}(2)(mu-OCPhCH=CHPhCH-PhCH=CPh-mu-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.

Original language	English
Pages (from-to)	1541-1543
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	10
DOIs	https://doi.org/10.1039/c1cc12869h
Publication status	Published - 2012

Keywords

electron transfer
dialkyl-amido sodium zincate
chalcone

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10.1039/c1cc12869h

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Armstrong, D. R., Balloch, L., Crawford, J. J., Fleming, B. J., Hogg, L. M., Kennedy, A. R., Klett, J., Mulvey, R. E., O'Hara, C. T., Orr, S. A., & Robertson, S. (2012). Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone. Chemical Communications, 48(10), 1541-1543. https://doi.org/10.1039/c1cc12869h

@article{a7d788dbcc864fb4988c3ef97cdf0cbe,

title = "Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone",

abstract = "More usually thought of as a base, the sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)center dot Na(mu-TMP)-(mu-TEMPO )Zn(Bu-t)] 2 and [(TMEDA)center dot Na(mu-TEMPO )(2)-Zn(Bu-t)] 3; and with chalcone [PhCOCH=CHPh] gives [\{(TMEDA)center dot Na(mu-TMP)Zn(Bu-t)\}(2)(mu-OCPhCH=CHPhCH-PhCH=CPh-mu-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.",

keywords = "electron transfer , dialkyl-amido sodium zincate , chalcone",

author = "Armstrong, \{D. R.\} and L. Balloch and Crawford, \{J. J.\} and Fleming, \{B. J.\} and Hogg, \{L. M.\} and Kennedy, \{A. R.\} and J. Klett and Mulvey, \{R. E.\} and O'Hara, \{C. T.\} and Orr, \{S. A.\} and Stuart Robertson",

year = "2012",

doi = "10.1039/c1cc12869h",

language = "English",

volume = "48",

pages = "1541--1543",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "10",

}

Armstrong, DR, Balloch, L, Crawford, JJ, Fleming, BJ, Hogg, LM, Kennedy, AR, Klett, J, Mulvey, RE , O'Hara, CT, Orr, SA & Robertson, S 2012, 'Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone', Chemical Communications, vol. 48, no. 10, pp. 1541-1543. https://doi.org/10.1039/c1cc12869h

TY - JOUR

T1 - Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone

AU - Armstrong, D. R.

AU - Balloch, L.

AU - Crawford, J. J.

AU - Fleming, B. J.

AU - Hogg, L. M.

AU - Kennedy, A. R.

AU - Klett, J.

AU - Mulvey, R. E.

AU - O'Hara, C. T.

AU - Orr, S. A.

AU - Robertson, Stuart

PY - 2012

Y1 - 2012

N2 - More usually thought of as a base, the sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)center dot Na(mu-TMP)-(mu-TEMPO )Zn(Bu-t)] 2 and [(TMEDA)center dot Na(mu-TEMPO )(2)-Zn(Bu-t)] 3; and with chalcone [PhCOCH=CHPh] gives [{(TMEDA)center dot Na(mu-TMP)Zn(Bu-t)}(2)(mu-OCPhCH=CHPhCH-PhCH=CPh-mu-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.

AB - More usually thought of as a base, the sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)center dot Na(mu-TMP)-(mu-TEMPO )Zn(Bu-t)] 2 and [(TMEDA)center dot Na(mu-TEMPO )(2)-Zn(Bu-t)] 3; and with chalcone [PhCOCH=CHPh] gives [{(TMEDA)center dot Na(mu-TMP)Zn(Bu-t)}(2)(mu-OCPhCH=CHPhCH-PhCH=CPh-mu-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.

KW - electron transfer

KW - dialkyl-amido sodium zincate

KW - chalcone

UR - https://www.scopus.com/pages/publications/84855657196

U2 - 10.1039/c1cc12869h

DO - 10.1039/c1cc12869h

M3 - Article

SN - 1359-7345

VL - 48

SP - 1541

EP - 1543

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone

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Chiral Concepts in s-Block Metal Amide Chemistry

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Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone

Abstract

Keywords

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