Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone

D. R. Armstrong, L. Balloch, J. J. Crawford, B. J. Fleming, L. M. Hogg, A. R. Kennedy, J. Klett, R. E. Mulvey, C. T. O'Hara, S. A. Orr, Stuart Robertson

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

More usually thought of as a base, the sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)center dot Na(mu-TMP)-(mu-TEMPO )Zn(Bu-t)] 2 and [(TMEDA)center dot Na(mu-TEMPO )(2)-Zn(Bu-t)] 3; and with chalcone [PhCOCH=CHPh] gives [{(TMEDA)center dot Na(mu-TMP)Zn(Bu-t)}(2)(mu-OCPhCH=CHPhCH-PhCH=CPh-mu-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.

LanguageEnglish
Pages1541-1543
Number of pages3
JournalChemical Communications
Volume48
Issue number10
DOIs
Publication statusPublished - 2012

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Chalcone
Sodium
Thymidine Monophosphate
Atoms
Electrons
phenyllithium
Na(mu-(t)Bu)(mu-TMP)Zn((t)Bu)
TEMPO

Keywords

  • electron transfer
  • dialkyl-amido sodium zincate
  • chalcone

Cite this

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title = "Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone",
abstract = "More usually thought of as a base, the sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)center dot Na(mu-TMP)-(mu-TEMPO )Zn(Bu-t)] 2 and [(TMEDA)center dot Na(mu-TEMPO )(2)-Zn(Bu-t)] 3; and with chalcone [PhCOCH=CHPh] gives [{(TMEDA)center dot Na(mu-TMP)Zn(Bu-t)}(2)(mu-OCPhCH=CHPhCH-PhCH=CPh-mu-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.",
keywords = "electron transfer , dialkyl-amido sodium zincate , chalcone",
author = "Armstrong, {D. R.} and L. Balloch and Crawford, {J. J.} and Fleming, {B. J.} and Hogg, {L. M.} and Kennedy, {A. R.} and J. Klett and Mulvey, {R. E.} and O'Hara, {C. T.} and Orr, {S. A.} and Stuart Robertson",
year = "2012",
doi = "10.1039/c1cc12869h",
language = "English",
volume = "48",
pages = "1541--1543",
journal = "Chemical Communications",
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number = "10",

}

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone. / Armstrong, D. R.; Balloch, L.; Crawford, J. J.; Fleming, B. J.; Hogg, L. M.; Kennedy, A. R.; Klett, J.; Mulvey, R. E.; O'Hara, C. T.; Orr, S. A.; Robertson, Stuart.

In: Chemical Communications, Vol. 48, No. 10, 2012, p. 1541-1543.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone

AU - Armstrong, D. R.

AU - Balloch, L.

AU - Crawford, J. J.

AU - Fleming, B. J.

AU - Hogg, L. M.

AU - Kennedy, A. R.

AU - Klett, J.

AU - Mulvey, R. E.

AU - O'Hara, C. T.

AU - Orr, S. A.

AU - Robertson, Stuart

PY - 2012

Y1 - 2012

N2 - More usually thought of as a base, the sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)center dot Na(mu-TMP)-(mu-TEMPO )Zn(Bu-t)] 2 and [(TMEDA)center dot Na(mu-TEMPO )(2)-Zn(Bu-t)] 3; and with chalcone [PhCOCH=CHPh] gives [{(TMEDA)center dot Na(mu-TMP)Zn(Bu-t)}(2)(mu-OCPhCH=CHPhCH-PhCH=CPh-mu-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.

AB - More usually thought of as a base, the sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] 1 can undergo single electron transfer with TEMPO to give [(TMEDA)center dot Na(mu-TMP)-(mu-TEMPO )Zn(Bu-t)] 2 and [(TMEDA)center dot Na(mu-TEMPO )(2)-Zn(Bu-t)] 3; and with chalcone [PhCOCH=CHPh] gives [{(TMEDA)center dot Na(mu-TMP)Zn(Bu-t)}(2)(mu-OCPhCH=CHPhCH-PhCH=CPh-mu-O)] which contains two chalcone units C-C coupled though their benzylic C atoms.

KW - electron transfer

KW - dialkyl-amido sodium zincate

KW - chalcone

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