Self-sustaining smoldering combustion for NAPL remediation: laboratory evaluation of process sensitivity to key parameters

Paolo Pironi, Christine Switzer, Jason I. Gerhard, Guillermo Rein, Jose L. Torero

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Smoldering combustion has been introduced recently as a potential remediation
strategy for soil contaminated by nonaqueous phase liquids (NAPLs). Published proof-of-concept experiments demonstrated that the process can be self-sustaining (i.e., requires energy input only to start the process) and achieve essentially complete remediation of the contaminated soil. Those initial experiments indicated that the process may be applicable across a broad range of NAPLs and soils. This work presents the results of a series of bench-scale experiments that examine in detail the sensitivity of the process to a range of key parameters, including contaminant concentration, water saturation, soil type, and air flow rates for two contaminants, coal tar and crude oil. Smoldering combustion was observed to be self-sustaining in the range 28,400 to 142,000 mg/kg for coal tar and in the range 31,200 to 104,000 mg/kg for crude oil, for the base case air flux. The process remained self-sustaining and achieved effective remediation across a range of initial water concentrations (0 to 177,000 mg/kg water) despite extended ignition times and decreased temperatures and velocities of the reaction front. The process also exhibited self-sustaining and effective remediation behavior across a range of fine to coarse sand grain sizes up to a threshold maximum value between 6 mm and 10 mm. Propagation velocity is observed to be highly dependent on air flux, and smoldering was observed to be self-sustaining down to an air Darcy flux of at least 0.5 cm/s for both contaminants. The extent of remediation in these cases was determined to be at least 99.5%and 99.9%for crude oil and coal tar, respectively. Moreover, no physical evidence of contamination was detected in the treatment zone for any case where a self-sustaining reaction was achieved. Lateral heat losses to the external environment were observed to significantly affect the smoldering process at the bench scale, suggesting that the field-scale lower bounds on concentration and air flux and upper bound on grain size were not achieved; larger scale experiments and field trials where lateral heat losses are much less significant are necessary to define these process limits for the purposes of field application. This work provides valuable design data for pilot field trials of both in situ and ex situ smoldering remediation applications.
LanguageEnglish
Pages2980-2986
Number of pages7
JournalEnvironmental Science and Technology
Volume45
Issue number7
Early online date25 Feb 2011
DOIs
Publication statusPublished - 1 Apr 2011

Fingerprint

nonaqueous phase liquid
Remediation
Coal Tar
remediation
combustion
coal tar
Petroleum
Fluxes
Liquids
crude oil
Soils
Air
air
Impurities
Heat losses
pollutant
Water
grain size
experiment
Experiments

Keywords

  • smoldering combustion
  • soil
  • sand grain sizes
  • heat loss

Cite this

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title = "Self-sustaining smoldering combustion for NAPL remediation: laboratory evaluation of process sensitivity to key parameters",
abstract = "Smoldering combustion has been introduced recently as a potential remediation strategy for soil contaminated by nonaqueous phase liquids (NAPLs). Published proof-of-concept experiments demonstrated that the process can be self-sustaining (i.e., requires energy input only to start the process) and achieve essentially complete remediation of the contaminated soil. Those initial experiments indicated that the process may be applicable across a broad range of NAPLs and soils. This work presents the results of a series of bench-scale experiments that examine in detail the sensitivity of the process to a range of key parameters, including contaminant concentration, water saturation, soil type, and air flow rates for two contaminants, coal tar and crude oil. Smoldering combustion was observed to be self-sustaining in the range 28,400 to 142,000 mg/kg for coal tar and in the range 31,200 to 104,000 mg/kg for crude oil, for the base case air flux. The process remained self-sustaining and achieved effective remediation across a range of initial water concentrations (0 to 177,000 mg/kg water) despite extended ignition times and decreased temperatures and velocities of the reaction front. The process also exhibited self-sustaining and effective remediation behavior across a range of fine to coarse sand grain sizes up to a threshold maximum value between 6 mm and 10 mm. Propagation velocity is observed to be highly dependent on air flux, and smoldering was observed to be self-sustaining down to an air Darcy flux of at least 0.5 cm/s for both contaminants. The extent of remediation in these cases was determined to be at least 99.5{\%}and 99.9{\%}for crude oil and coal tar, respectively. Moreover, no physical evidence of contamination was detected in the treatment zone for any case where a self-sustaining reaction was achieved. Lateral heat losses to the external environment were observed to significantly affect the smoldering process at the bench scale, suggesting that the field-scale lower bounds on concentration and air flux and upper bound on grain size were not achieved; larger scale experiments and field trials where lateral heat losses are much less significant are necessary to define these process limits for the purposes of field application. This work provides valuable design data for pilot field trials of both in situ and ex situ smoldering remediation applications.",
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Self-sustaining smoldering combustion for NAPL remediation : laboratory evaluation of process sensitivity to key parameters. / Pironi, Paolo; Switzer, Christine; Gerhard, Jason I.; Rein, Guillermo; Torero, Jose L.

In: Environmental Science and Technology, Vol. 45, No. 7, 01.04.2011, p. 2980-2986.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Self-sustaining smoldering combustion for NAPL remediation

T2 - Environmental Science and Technology

AU - Pironi, Paolo

AU - Switzer, Christine

AU - Gerhard, Jason I.

AU - Rein, Guillermo

AU - Torero, Jose L.

PY - 2011/4/1

Y1 - 2011/4/1

N2 - Smoldering combustion has been introduced recently as a potential remediation strategy for soil contaminated by nonaqueous phase liquids (NAPLs). Published proof-of-concept experiments demonstrated that the process can be self-sustaining (i.e., requires energy input only to start the process) and achieve essentially complete remediation of the contaminated soil. Those initial experiments indicated that the process may be applicable across a broad range of NAPLs and soils. This work presents the results of a series of bench-scale experiments that examine in detail the sensitivity of the process to a range of key parameters, including contaminant concentration, water saturation, soil type, and air flow rates for two contaminants, coal tar and crude oil. Smoldering combustion was observed to be self-sustaining in the range 28,400 to 142,000 mg/kg for coal tar and in the range 31,200 to 104,000 mg/kg for crude oil, for the base case air flux. The process remained self-sustaining and achieved effective remediation across a range of initial water concentrations (0 to 177,000 mg/kg water) despite extended ignition times and decreased temperatures and velocities of the reaction front. The process also exhibited self-sustaining and effective remediation behavior across a range of fine to coarse sand grain sizes up to a threshold maximum value between 6 mm and 10 mm. Propagation velocity is observed to be highly dependent on air flux, and smoldering was observed to be self-sustaining down to an air Darcy flux of at least 0.5 cm/s for both contaminants. The extent of remediation in these cases was determined to be at least 99.5%and 99.9%for crude oil and coal tar, respectively. Moreover, no physical evidence of contamination was detected in the treatment zone for any case where a self-sustaining reaction was achieved. Lateral heat losses to the external environment were observed to significantly affect the smoldering process at the bench scale, suggesting that the field-scale lower bounds on concentration and air flux and upper bound on grain size were not achieved; larger scale experiments and field trials where lateral heat losses are much less significant are necessary to define these process limits for the purposes of field application. This work provides valuable design data for pilot field trials of both in situ and ex situ smoldering remediation applications.

AB - Smoldering combustion has been introduced recently as a potential remediation strategy for soil contaminated by nonaqueous phase liquids (NAPLs). Published proof-of-concept experiments demonstrated that the process can be self-sustaining (i.e., requires energy input only to start the process) and achieve essentially complete remediation of the contaminated soil. Those initial experiments indicated that the process may be applicable across a broad range of NAPLs and soils. This work presents the results of a series of bench-scale experiments that examine in detail the sensitivity of the process to a range of key parameters, including contaminant concentration, water saturation, soil type, and air flow rates for two contaminants, coal tar and crude oil. Smoldering combustion was observed to be self-sustaining in the range 28,400 to 142,000 mg/kg for coal tar and in the range 31,200 to 104,000 mg/kg for crude oil, for the base case air flux. The process remained self-sustaining and achieved effective remediation across a range of initial water concentrations (0 to 177,000 mg/kg water) despite extended ignition times and decreased temperatures and velocities of the reaction front. The process also exhibited self-sustaining and effective remediation behavior across a range of fine to coarse sand grain sizes up to a threshold maximum value between 6 mm and 10 mm. Propagation velocity is observed to be highly dependent on air flux, and smoldering was observed to be self-sustaining down to an air Darcy flux of at least 0.5 cm/s for both contaminants. The extent of remediation in these cases was determined to be at least 99.5%and 99.9%for crude oil and coal tar, respectively. Moreover, no physical evidence of contamination was detected in the treatment zone for any case where a self-sustaining reaction was achieved. Lateral heat losses to the external environment were observed to significantly affect the smoldering process at the bench scale, suggesting that the field-scale lower bounds on concentration and air flux and upper bound on grain size were not achieved; larger scale experiments and field trials where lateral heat losses are much less significant are necessary to define these process limits for the purposes of field application. This work provides valuable design data for pilot field trials of both in situ and ex situ smoldering remediation applications.

KW - smoldering combustion

KW - soil

KW - sand grain sizes

KW - heat loss

U2 - 10.1021/es102969z

DO - 10.1021/es102969z

M3 - Article

VL - 45

SP - 2980

EP - 2986

JO - Environmental Science and Technology

JF - Environmental Science and Technology

SN - 0013-936X

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ER -