Abstract
| Language | English |
|---|---|
| Pages | 69-98 |
| Number of pages | 29 |
| Journal | Chemical Society Reviews |
| Volume | 34 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 2005 |
Fingerprint
Keywords
- pi-electron donors
- ray crystal-structures
- charge-transfer salts
- cation-radical salts
- functionalized 9
- 10-bis(1
- 3-dithiol-2-ylidene)-9
- 10-dihydroanthracene derivatives
- metals (bedt-atd)(2)x(solvent) x
- pressure organic superconductor
- bis-fused tetrathiafulvalene
- bedt-ttf
- conducting properties
Cite this
}
Salts of extended tetrathiafulvalene analogues: relationships between molecular structure, electrochemical properties and solid state organisation. / Frere, P.; Skabara, P.J.
In: Chemical Society Reviews, Vol. 34, No. 1, 01.2005, p. 69-98.Research output: Contribution to journal › Article
TY - JOUR
T1 - Salts of extended tetrathiafulvalene analogues: relationships between molecular structure, electrochemical properties and solid state organisation
AU - Frere, P.
AU - Skabara, P.J.
PY - 2005/1
Y1 - 2005/1
N2 - By considering the structures of many salts derived from extended TTF analogues, relationships between the molecular architecture of the donors with their electrochemical properties and their stacking mode in the salts are presented in this critical review. Three categories of donors corresponding to their extension modes have been considered. Firstly, for linearly extended TTFs the crucial role of the spacer in modifying the electrochemical properties and the packing mode in the salts is presented. Secondly, bidimentional extension of the donors obtained by linking several dithiafulvenyl units on a TTF core led to materials with increased dimensionality. Finally, the last class corresponds to the fusion, directly or across a benzene ring, of TTF frameworks. The former are the base of many salts with metallic behaviour.
AB - By considering the structures of many salts derived from extended TTF analogues, relationships between the molecular architecture of the donors with their electrochemical properties and their stacking mode in the salts are presented in this critical review. Three categories of donors corresponding to their extension modes have been considered. Firstly, for linearly extended TTFs the crucial role of the spacer in modifying the electrochemical properties and the packing mode in the salts is presented. Secondly, bidimentional extension of the donors obtained by linking several dithiafulvenyl units on a TTF core led to materials with increased dimensionality. Finally, the last class corresponds to the fusion, directly or across a benzene ring, of TTF frameworks. The former are the base of many salts with metallic behaviour.
KW - pi-electron donors
KW - ray crystal-structures
KW - charge-transfer salts
KW - cation-radical salts
KW - functionalized 9
KW - 10-bis(1
KW - 3-dithiol-2-ylidene)-9
KW - 10-dihydroanthracene derivatives
KW - metals (bedt-atd)(2)x(solvent) x
KW - pressure organic superconductor
KW - bis-fused tetrathiafulvalene
KW - bedt-ttf
KW - conducting properties
UR - http://www.rsc.org/ej/CS/2005/b316392j.pdf
UR - http://dx.doi.org/10.1039/b316392j
U2 - 10.1039/b316392j
DO - 10.1039/b316392j
M3 - Article
VL - 34
SP - 69
EP - 98
JO - Chemical Society Reviews
T2 - Chemical Society Reviews
JF - Chemical Society Reviews
SN - 0306-0012
IS - 1
ER -