Role of the organic linker in the early stages of the templated synthesis of PMOs

Ryusuke Futamura, Miguel Jorge, José R B Gomes

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Classical MD simulations for surfactant-bromide-water solutions containing several organosilicate precursors show that the presence or absence of molecular-scale periodicity in the pore walls of PMOs is dictated by the strength of the surfactant micelle-organosilica interaction and by the relative flexibility and orientation of the organic linker.

LanguageEnglish
Pages6166-6169
Number of pages4
JournalPhysical Chemistry Chemical Physics
Volume15
Issue number17
DOIs
Publication statusPublished - 7 May 2013

Fingerprint

Surface-Active Agents
surfactants
Micelles
synthesis
Bromides
bromides
periodic variations
micelles
flexibility
porosity
Water
water
simulation
interactions

Keywords

  • organic linker
  • periodic mesoporous organosilicas
  • PMOs

Cite this

@article{1f89eb2a17094c36bba4af21b95fc7e4,
title = "Role of the organic linker in the early stages of the templated synthesis of PMOs",
abstract = "Classical MD simulations for surfactant-bromide-water solutions containing several organosilicate precursors show that the presence or absence of molecular-scale periodicity in the pore walls of PMOs is dictated by the strength of the surfactant micelle-organosilica interaction and by the relative flexibility and orientation of the organic linker.",
keywords = "organic linker, periodic mesoporous organosilicas, PMOs",
author = "Ryusuke Futamura and Miguel Jorge and Gomes, {Jos{\'e} R B}",
year = "2013",
month = "5",
day = "7",
doi = "10.1039/c3cp50193k",
language = "English",
volume = "15",
pages = "6166--6169",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
number = "17",

}

Role of the organic linker in the early stages of the templated synthesis of PMOs. / Futamura, Ryusuke; Jorge, Miguel; Gomes, José R B.

In: Physical Chemistry Chemical Physics, Vol. 15, No. 17, 07.05.2013, p. 6166-6169.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Role of the organic linker in the early stages of the templated synthesis of PMOs

AU - Futamura, Ryusuke

AU - Jorge, Miguel

AU - Gomes, José R B

PY - 2013/5/7

Y1 - 2013/5/7

N2 - Classical MD simulations for surfactant-bromide-water solutions containing several organosilicate precursors show that the presence or absence of molecular-scale periodicity in the pore walls of PMOs is dictated by the strength of the surfactant micelle-organosilica interaction and by the relative flexibility and orientation of the organic linker.

AB - Classical MD simulations for surfactant-bromide-water solutions containing several organosilicate precursors show that the presence or absence of molecular-scale periodicity in the pore walls of PMOs is dictated by the strength of the surfactant micelle-organosilica interaction and by the relative flexibility and orientation of the organic linker.

KW - organic linker

KW - periodic mesoporous organosilicas

KW - PMOs

UR - http://www.scopus.com/inward/record.url?scp=84875853004&partnerID=8YFLogxK

U2 - 10.1039/c3cp50193k

DO - 10.1039/c3cp50193k

M3 - Article

VL - 15

SP - 6166

EP - 6169

JO - Physical Chemistry Chemical Physics

T2 - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 17

ER -