Robust microelectrodes in molten salt analysis

Andrew Relf; Damion Corrigan; Charlotte L Brady; Jonathan G Terry; Antony J Walton; Andrew R Mount

doi:10.1149/05011.0105ecst

Robust microelectrodes in molten salt analysis

Andrew Relf, Damion Corrigan, Charlotte L Brady, Jonathan G Terry, Antony J Walton, Andrew R Mount

Biomedical Engineering

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Molten salts have proven to be an ideal medium for the development of a number of electrochemical processes. However, there is a real need in such processes for techniques to be developed which are able to sense and analyse the properties of redox active species in the extreme conditions found in molten salts. This paper reports the work undertaken to develop a system for the characterisation of microelectrodes in molten LiCl-KCl eutectic and demonstrates for the first time using the Ag+/Ag plating/stripping system the production and characterisation of microelectrodes through photolithography which are able to measure redox characteristics with the expected enhanced characteristics compared to macroelectrode measurements.

Original language	English
Pages (from-to)	105-109
Number of pages	5
Journal	ECS Transactions
Volume	50
Issue number	11
DOIs	https://doi.org/10.1149/05011.0105ecst
Publication status	Published - 4 Jun 2012

Keywords

electrochemical process
extreme conditions
LiCI-KCI eutectic
molten salt
redox-active

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10.1149/05011.0105ecst

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abstract = "Molten salts have proven to be an ideal medium for the development of a number of electrochemical processes. However, there is a real need in such processes for techniques to be developed which are able to sense and analyse the properties of redox active species in the extreme conditions found in molten salts. This paper reports the work undertaken to develop a system for the characterisation of microelectrodes in molten LiCl-KCl eutectic and demonstrates for the first time using the Ag+/Ag plating/stripping system the production and characterisation of microelectrodes through photolithography which are able to measure redox characteristics with the expected enhanced characteristics compared to macroelectrode measurements.",

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AU - Relf, Andrew

AU - Corrigan, Damion

AU - Brady, Charlotte L

AU - Terry, Jonathan G

AU - Walton, Antony J

AU - Mount, Andrew R

PY - 2012/6/4

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N2 - Molten salts have proven to be an ideal medium for the development of a number of electrochemical processes. However, there is a real need in such processes for techniques to be developed which are able to sense and analyse the properties of redox active species in the extreme conditions found in molten salts. This paper reports the work undertaken to develop a system for the characterisation of microelectrodes in molten LiCl-KCl eutectic and demonstrates for the first time using the Ag+/Ag plating/stripping system the production and characterisation of microelectrodes through photolithography which are able to measure redox characteristics with the expected enhanced characteristics compared to macroelectrode measurements.

AB - Molten salts have proven to be an ideal medium for the development of a number of electrochemical processes. However, there is a real need in such processes for techniques to be developed which are able to sense and analyse the properties of redox active species in the extreme conditions found in molten salts. This paper reports the work undertaken to develop a system for the characterisation of microelectrodes in molten LiCl-KCl eutectic and demonstrates for the first time using the Ag+/Ag plating/stripping system the production and characterisation of microelectrodes through photolithography which are able to measure redox characteristics with the expected enhanced characteristics compared to macroelectrode measurements.

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Robust microelectrodes in molten salt analysis

Abstract

Keywords

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