Reversible, fluorescence-based optical sensor for hydrogen peroxide

A. Mills, Cheryl Tommons, R.T. Bailey, M.Catriona Tedford, Peter J. Crilly

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22 Citations (Scopus)

Abstract

The preparation and characterisation are described of a robust, reversible, hydrogen peroxide optical sensor, based on the fluorescent quenching of the dye ion-pair [Ru(bpy)32+(Ph4B-)2], by O2 produced by the catalytic breakdown of H2O2, utilizing the inorganic catalyst RuO2·xH2O. The main feature of this system is the one-pot formulation of a coating ink that, when dried, forms an active single-layer fluorescence-based H2O2 sensor, demonstrably capable of detecting H2O2 over the range of 0.01 to 1 M, with a relative standard deviation of ca. 4% and a calculated lower limit of detection of 0.1 mM. These sensors are sterilisable, using dry-heat, and stable when stored over 40 days, without exhibiting any loss in sensitivity or response characteristics.
Original languageEnglish
Pages (from-to)566-571
Number of pages5
JournalAnalyst
Volume132
Issue number6
DOIs
Publication statusPublished - 2007

Keywords

  • fluorescence-based optical sensor
  • hydrogen peroxide
  • optical sensor
  • dye

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  • Cite this

    Mills, A., Tommons, C., Bailey, R. T., Tedford, M. C., & Crilly, P. J. (2007). Reversible, fluorescence-based optical sensor for hydrogen peroxide. Analyst, 132(6), 566-571. https://doi.org/10.1039/b618506a