Resonance raman excitation profile of cobalt phthalocyanine at room-temperature and 10-k

C.R. Bartholomew, A.A. McConnell, W.E. Smith

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12 Citations (Scopus)

Abstract

Resonance excitation profiles have been obtained for cobalt phthalecyanine at both room temperature and 10 K using a compressed disc of silver and the phthalocyanine. Low-frequency vibrations are shown to be influenced mainly by displacements on the bonding nitrogen, but high-frequency vibrations show a more complex pattern with some evidence that the vibrations v3 and v28 depend on C displacements. By comparison with copper, there appears to be a greater degree of scattering from 0-0 and 0-1 transitions and there is a shift towards increase 0-0 scattering in the sharper low-temperature profiles. It is concluded that a distortion, dynamic at room temperature and static at low temperature, plays a key role in determining the relative scattering and this distortion is larger for copper phthalocyanine than for cobalt phthalocyanine.
Original languageEnglish
Pages (from-to)595-600
Number of pages5
JournalJournal of Raman Spectroscopy
Volume20
Issue number9
DOIs
Publication statusPublished - Sep 1989

Keywords

  • resonance excitation profiles
  • cobalt phthalecyanine
  • silver
  • phthalocyanine
  • low-frequency vibrations
  • nitrogen
  • high-frequency vibrations

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