Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores

A R  Kennedy; R E  Mulvey; R B  Rowlings

doi:10.1002/(SICI)1521-3773(19981204)37:22<3180::AID-ANIE3180>3.0.CO;2-D

Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores

A R Kennedy, R E Mulvey, R B Rowlings

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

74 Citations (Scopus)

Abstract

Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium-substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].

Original language	English
Pages (from-to)	3180-3183
Number of pages	4
Journal	Agewandte Chemie-International Edition
Volume	37
Issue number	22
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19981204)37:22<3180::AID-ANIE3180>3.0.CO;2-D
Publication status	Published - 1998

Keywords

alkali metals
amides
heterodimetallic compounds
oxygenations
structure elucidation

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10.1002/(SICI)1521-3773(19981204)37:22<3180::AID-ANIE3180>3.0.CO;2-D

x-ray diffractometer
Kennedy, A.
Pure And Applied Chemistry
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abstract = "Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium-substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].",

keywords = "alkali metals, amides, heterodimetallic compounds, oxygenations, structure elucidation",

author = "Kennedy, {A R} and Mulvey, {R E} and Rowlings, {R B}",

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T1 - Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores

AU - Kennedy, A R

AU - Mulvey, R E

AU - Rowlings, R B

PY - 1998

Y1 - 1998

N2 - Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium-substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].

AB - Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium-substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].

KW - alkali metals

KW - amides

KW - heterodimetallic compounds

KW - oxygenations

KW - structure elucidation

U2 - 10.1002/(SICI)1521-3773(19981204)37:22<3180::AID-ANIE3180>3.0.CO;2-D

DO - 10.1002/(SICI)1521-3773(19981204)37:22<3180::AID-ANIE3180>3.0.CO;2-D

M3 - Article

SN - 1433-7851

VL - 37

SP - 3180

EP - 3183

JO - Agewandte Chemie-International Edition

JF - Agewandte Chemie-International Edition

IS - 22

ER -

Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores

Abstract

Keywords

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