Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores

A R Kennedy, R E Mulvey, R B Rowlings

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Abstract

Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium-substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].
LanguageEnglish
Pages3180-3183
Number of pages4
JournalAgewandte Chemie-International Edition
Volume37
Issue number22
DOIs
Publication statusPublished - 1998

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Sodium Compounds
Sodium compounds
Alkali Metals
Molecular oxygen
Alkali metals
Amides
Magnesium
Amines
Metals
Oxygen
Derivatives

Keywords

  • alkali metals
  • amides
  • heterodimetallic compounds
  • oxygenations
  • structure elucidation

Cite this

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abstract = "Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium-substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].",
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author = "Kennedy, {A R} and Mulvey, {R E} and Rowlings, {R B}",
year = "1998",
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T1 - Remarkable reaction of hetero-S-block-metal amides with molecular oxygen: Cationic (NMNMg)(2) ring products (M = Li or Na) with anionic oxo or peroxo cores

AU - Kennedy, A R

AU - Mulvey, R E

AU - Rowlings, R B

PY - 1998

Y1 - 1998

N2 - Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium-substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].

AB - Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium-substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].

KW - alkali metals

KW - amides

KW - heterodimetallic compounds

KW - oxygenations

KW - structure elucidation

U2 - 10.1002/(SICI)1521-3773(19981204)37:22<3180::AID-ANIE3180>3.0.CO;2-D

DO - 10.1002/(SICI)1521-3773(19981204)37:22<3180::AID-ANIE3180>3.0.CO;2-D

M3 - Article

VL - 37

SP - 3180

EP - 3183

JO - Angewandte Chemie International Edition

T2 - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 22

ER -